PMID- 18371664
OWN - NLM
STAT- MEDLINE
DCOM- 20080826
LR  - 20121115
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 74
IP  - 4
DP  - 2008 Jan 15
TI  - Headspace single drop microextraction combined with HPLC for the determination of 
      trace polycyclic aromatic hydrocarbons in environmental samples.
PG  - 470-7
LID - 10.1016/j.talanta.2007.05.057 [doi]
AB  - A new method by combining headspace single drop microextraction (HS-SDME) with 
      HPLC fluorescence detection for the determination of trace polycyclic aromatic 
      hydrocarbons (PAHs) in environmental samples was developed. Aqueous solution of 
      saturated beta-cyclodextrin was used as extraction solvent and five PAHs were 
      employed as target analytes. The factors affecting the extraction efficiency were 
      studied in detail and the optimal extraction conditions were established. 
      Beta-cyclodextrin was found to play two important roles, one is the improvement 
      of extraction efficiency of target analytes and the other is the enhancement of 
      their fluorescence intensities in HPLC fluorescence detection. The detection 
      limits for the target analytes were found to be in the range of 0.004-0.247ng/ml 
      and the relative standard deviations (R.S.D.s) of 5.1-7.1% were obtained. The 
      proposed method was applied to the analysis of trace PAHs in environmental 
      samples with satisfactory results.
FAU - Wu, Yunli
AU  - Wu Y
AD  - Department of Chemistry, Wuhan University, Wuhan 430072, China.
FAU - Xia, Linbo
AU  - Xia L
FAU - Chen, Rui
AU  - Chen R
FAU - Hu, Bin
AU  - Hu B
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20070623
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Environmental Pollutants)
RN  - 0 (Polycyclic Compounds)
RN  - 0 (beta-Cyclodextrins)
RN  - JV039JZZ3A (betadex)
SB  - IM
MH  - Chromatography, High Pressure Liquid/*methods
MH  - Environmental Pollutants/*analysis
MH  - Hydrogen-Ion Concentration
MH  - Osmolar Concentration
MH  - Plant Leaves/chemistry
MH  - Polycyclic Compounds/*analysis
MH  - Spectrometry, Fluorescence
MH  - beta-Cyclodextrins/chemistry
EDAT- 2008/03/29 09:00
MHDA- 2008/08/30 09:00
CRDT- 2008/03/29 09:00
PHST- 2007/03/27 00:00 [received]
PHST- 2007/05/31 00:00 [revised]
PHST- 2007/05/31 00:00 [accepted]
PHST- 2008/03/29 09:00 [pubmed]
PHST- 2008/08/30 09:00 [medline]
PHST- 2008/03/29 09:00 [entrez]
AID - S0039-9140(07)00419-5 [pii]
AID - 10.1016/j.talanta.2007.05.057 [doi]
PST - ppublish
SO  - Talanta. 2008 Jan 15;74(4):470-7. doi: 10.1016/j.talanta.2007.05.057. Epub 2007 
      Jun 23.