PMID- 18419175 OWN - NLM STAT- MEDLINE DCOM- 20090202 LR - 20161018 IS - 0730-7268 (Print) IS - 0730-7268 (Linking) VI - 27 IP - 10 DP - 2008 Oct TI - Concentrations and patterns of perfluoroalkyl acids in Georgia, USA surface waters near and distant to a major use source. PG - 2011-8 LID - 10.1897/07-659.1 [doi] AB - Perfluoroalkyl acids (PFAAs) are widespread contaminants emanating from, among other sources, the production/degradation of fluorinated chemicals used in surface repellant applications, such as carpet manufacturing. The goal of the present study was to assess the concentrations of PFAAs, including perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), perfluorodecanoic acid (PFDA), perfluoroundecanoic acid (PFUA), and perfluorooctane sulfonamide (PFOSA), in surface waters both near a wastewater land application system (LAS) in Dalton (GA, USA), home to North America's largest carpet manufacturing site, and distant to this location (Altamaha River, GA, USA) to understand the fate of PFAAs in freshwater. Levels of PFAAs were high in the Conasauga River (GA, USA) downstream of the LAS (PFOA, 253-1,150 ng/L; PFOS, 192-318 ng/L; PFNA, 202-369 ng/L; PFDA, 30.1-113 ng/L; PFUA, 58.0-99.2 ng/L; PFOSA, 162-283 ng/L) and in streams and ponds in Dalton (PFOA, 49.9-299 ng/L; PFOS, 15.8-120 ng/L), and were among the highest measured at a nonspill or direct-release location. Perfluoroalkyl acids in the Altamaha River were much lower (PFOA, 3.0-3.1 ng/L; PFOS, 2.6-2.7 ng/L), but were a source of PFAAs to Georgia's estuaries. A preliminary hazard assessment indicated that concentrations of PFOS at two sites in the Conasauga River exceeded the threshold effect predicted for birds consuming aquatic organisms that are exposed continuously to the PFOS levels at these sites. Assuming that toxicity for all PFAAs quantified is equal to that of PFOS, the sum total PFAAs at two sites within the Conasauga River exceeded PFOS thresholds for aquatic and avian species, warranting additional research. FAU - Konwick, Brad J AU - Konwick BJ AD - Warnell School of Forestry and Natural Resources, University of Georgia, Athens, Georgia 30602, USA. FAU - Tomy, Gregg T AU - Tomy GT FAU - Ismail, Nargis AU - Ismail N FAU - Peterson, James T AU - Peterson JT FAU - Fauver, Rebecca J AU - Fauver RJ FAU - Higginbotham, David AU - Higginbotham D FAU - Fisk, Aaron T AU - Fisk AT LA - eng PT - Journal Article PL - United States TA - Environ Toxicol Chem JT - Environmental toxicology and chemistry JID - 8308958 RN - 0 (Fluorocarbons) RN - 0 (Industrial Waste) RN - 0 (Water Pollutants, Chemical) SB - IM MH - Chromatography, High Pressure Liquid MH - Fluorocarbons/*analysis MH - Fresh Water/analysis MH - Georgia MH - Industrial Waste/analysis MH - Quality Control MH - Reference Standards MH - Spectrometry, Mass, Electrospray Ionization MH - Water Pollutants, Chemical/*analysis EDAT- 2008/04/19 09:00 MHDA- 2009/02/03 09:00 CRDT- 2008/04/19 09:00 PHST- 2007/12/28 00:00 [received] PHST- 2008/04/02 00:00 [accepted] PHST- 2008/04/19 09:00 [pubmed] PHST- 2009/02/03 09:00 [medline] PHST- 2008/04/19 09:00 [entrez] AID - 07-659 [pii] AID - 10.1897/07-659.1 [doi] PST - ppublish SO - Environ Toxicol Chem. 2008 Oct;27(10):2011-8. doi: 10.1897/07-659.1.