PMID- 18476667
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20080804
LR  - 20080612
IS  - 0743-7463 (Print)
IS  - 0743-7463 (Linking)
VI  - 24
IP  - 12
DP  - 2008 Jun 17
TI  - Functionalization of glassy carbon with diazonium salts in ionic liquids.
PG  - 6327-33
LID - 10.1021/la703714a [doi]
AB  - The paper reports on the chemical functionalization of glassy carbon electrodes 
      with 4-bromobenzene (4-BBDT) and 4-(4'-nitrophenylazo)benzene diazonium 
      tetrafluoroborate (4-NAB) salts in ionic liquids. The reaction was carried out at 
      room temperature in air without any external electrical bias in either 
      hydrophobic (1-butyl-3-methylimidazolium hexafluorophosphate) or hydrophilic 
      (1-butyl-3-methylimidazolium methyl sulfate) ionic liquids. The resulting 
      surfaces were characterized using X-ray photoelectron spectroscopy (XPS), Raman 
      spectroscopy, and electrochemical measurements. Electrochemical reduction of the 
      terminal nitro groups allowed the determination of surface coverage and formation 
      of an amine-terminated carbon surfaces. The results were compared to glassy 
      carbon chemically modified in an aqueous solution in the presence of 1% sodium 
      dodecyl sulfate (SDS) with the same diazonium salt. Furthermore, Raman 
      spectroscopy coupled with electrochemical measurements allowed to distinguish 
      between the reduction of -NO2 to -NH2 group and the -N=N- to -NH-NH- bond.
FAU - Actis, Paolo
AU  - Actis P
AD  - Laboratoire d'Electrochimie et de Physicochimie des Materiaux et des Interfaces, 
      CNRS-INPG-UJF, 1130 Rue de la Piscine, BP 75, 38402 St. Martin d'Heres Cedex, 
      France.
FAU - Caulliez, Guilain
AU  - Caulliez G
FAU - Shul, Galyna
AU  - Shul G
FAU - Opallo, Marcin
AU  - Opallo M
FAU - Mermoux, Michel
AU  - Mermoux M
FAU - Marcus, Bernadette
AU  - Marcus B
FAU - Boukherroub, Rabah
AU  - Boukherroub R
FAU - Szunerits, Sabine
AU  - Szunerits S
LA  - eng
PT  - Journal Article
DEP - 20080513
PL  - United States
TA  - Langmuir
JT  - Langmuir : the ACS journal of surfaces and colloids
JID - 9882736
EDAT- 2008/05/15 09:00
MHDA- 2008/05/15 09:01
CRDT- 2008/05/15 09:00
PHST- 2008/05/15 09:00 [pubmed]
PHST- 2008/05/15 09:01 [medline]
PHST- 2008/05/15 09:00 [entrez]
AID - 10.1021/la703714a [doi]
PST - ppublish
SO  - Langmuir. 2008 Jun 17;24(12):6327-33. doi: 10.1021/la703714a. Epub 2008 May 13.