PMID- 18558129
OWN - NLM
STAT- MEDLINE
DCOM- 20080717
LR  - 20131121
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 620
IP  - 1-2
DP  - 2008 Jul 14
TI  - Faster and simpler determination of chlorophenols in water by fiber introduction 
      mass spectrometry.
PG  - 97-102
LID - 10.1016/j.aca.2008.05.033 [doi]
AB  - Solid phase microextraction (SPME) of chlorophenols [2-chlorophenol (2CP), 
      2,4-dichlorophenol (24CP), 4-chloro-3-methylphenol (43CP), 2,4,6-tri-chlorophenol 
      (246CP) and pentachlorophenol (PCP)] followed by direct mass spectrometric 
      analysis has been performed by fiber introduction mass spectrometry (FIMS). Two 
      SPME fibers (65 microm PDMS/DVB and 85 microm PA fibers) were tested, and FIMS 
      was performed via selective ion monitoring (SIM). The extractions were evaluated 
      at 10% ionic strength and pH 1. Best extraction times were determined for both 
      fibers. Limits of detection (LOD) and limits of quantification (LOQ) for both 
      fibers were in the low microg L(-1) range. Coefficients of correlation for the 
      analytical curves showed linear responses and mineral water and river water 
      samples spiked with 50 microg L(-1) presented high recoveries. FIMS, as compared 
      to current EPA methods, is demonstrated to allow faster and simpler (elimination 
      of pre-separation or derivatization steps) analysis of chlorophenols in water 
      with the required sensitivity.
FAU - Eberlin, Marcos Nogueira
AU  - Eberlin MN
AD  - ThoMSon Mass Spectrometry Laboratory, Institute of Chemistry, State University of 
      Campinas, 13084-971 Campinas, SP, Brazil.
FAU - Cesar da Silva, Rogerio
AU  - Cesar da Silva R
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20080522
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
RN  - 0 (Chlorophenols)
RN  - 059QF0KO0R (Water)
SB  - IM
MH  - Chlorophenols/*analysis
MH  - Hydrogen-Ion Concentration
MH  - Mass Spectrometry/*instrumentation/*methods
MH  - Osmolar Concentration
MH  - Solid Phase Extraction
MH  - Time Factors
MH  - Water/*chemistry
EDAT- 2008/06/19 09:00
MHDA- 2008/07/18 09:00
CRDT- 2008/06/19 09:00
PHST- 2008/01/21 00:00 [received]
PHST- 2008/04/11 00:00 [revised]
PHST- 2008/05/18 00:00 [accepted]
PHST- 2008/06/19 09:00 [pubmed]
PHST- 2008/07/18 09:00 [medline]
PHST- 2008/06/19 09:00 [entrez]
AID - S0003-2670(08)00955-0 [pii]
AID - 10.1016/j.aca.2008.05.033 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2008 Jul 14;620(1-2):97-102. doi: 10.1016/j.aca.2008.05.033. Epub 
      2008 May 22.