PMID- 18573516 OWN - NLM STAT- MEDLINE DCOM- 20080930 LR - 20190423 IS - 0045-6535 (Print) IS - 0045-6535 (Linking) VI - 72 IP - 10 DP - 2008 Aug TI - Spatial trends of polyfluorinated compounds in guillemot (Uria aalge) eggs from North-Western Europe. PG - 1475-1480 LID - S0045-6535(08)00631-0 [pii] LID - 10.1016/j.chemosphere.2008.05.011 [doi] AB - Polyfluorinated alkyl compounds (PFCs) are a group of chemicals of growing concern that have been detected in biological and abiotic samples worldwide. This study reports the concentrations of a suite of PFCs: perfluorooctyl sulfonate (PFOS), perfluorooctyl sulfonamide (PFOSA) and perfluorinated carboxylic acids (PFCAs) in guillemot (Uria aalge) eggs, collected in North-Western Europe, from Iceland, the Faroe Islands, Sweden and two locations in Norway. The highest concentrations of PFOS were found in samples from Sweden (mean 400 ng g(-1) wet weight (w.w.)), which were almost five times higher than concentrations found in Norwegian samples (mean 85 ng g(-1)w.w. from both sample sites). The concentrations found in Icelandic and Faroe samples were lowest (mean 16 and 15 ng g(-1)w.w., respectively). Only Swedish samples differed significantly from the other locations. In general, PFCAs show a different spatial trend than PFOS. Perfluorooctanoic acid (PFOA) was not detected in any sample and perfluorononanoic acid (PFNA) was only detected in samples from Sweden. The most abundant PFCA was perfluoroundecanoic acid (PFUA) with highest concentrations in samples from Sweden (mean 82 ng g(-1)w.w.), samples from the Faroe Islands had the second highest concentration (mean 57 ng g(-1)w.w.) and samples from Iceland and Norway had concentrations ranging between 18 and 30 ng g(-1)w.w. The original hypothesis was based on the idea that PFC concentrations are the highest close to more densely populated and industrialized areas and lower levels in remote areas. However, the geographic pattern is more complicated than predicted and varies among different PFCs. FAU - Lofstrand, Karin AU - Lofstrand K AD - Department of Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden. FAU - Jorundsdottir, Hronn AU - Jorundsdottir H AD - Department of Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden. Electronic address: Hronn.Jorundsdottir@mk.su.se. FAU - Tomy, Gregg AU - Tomy G AD - Freshwater Institute, Department of Fisheries and Oceans, Winnipeg, Manitoba, Canada R3T 2N6. FAU - Svavarsson, Jorundur AU - Svavarsson J AD - Institute of Biology, University of Iceland, Askja, Sturlugata 7, 101 Reykjavik, Iceland. FAU - Weihe, Pal AU - Weihe P AD - Department of Occupational Medicine and Public Health, Faroese Hospital System, Torshavn, Faroe Islands. FAU - Nygard, Torgeir AU - Nygard T AD - Norwegian Institute for Nature Research, Tungasletta 2, N-7485 Trondheim, Norway. FAU - Bergman, Ake AU - Bergman A AD - Department of Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20080624 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Fluorocarbons) SB - IM MH - Animals MH - Charadriiformes/*metabolism MH - Eggs/*analysis MH - Environmental Monitoring MH - Fluorocarbons/*analysis/metabolism MH - Geography MH - Iceland MH - Norway MH - Sweden EDAT- 2008/06/25 09:00 MHDA- 2008/10/01 09:00 CRDT- 2008/06/25 09:00 PHST- 2007/11/24 00:00 [received] PHST- 2008/05/01 00:00 [revised] PHST- 2008/05/05 00:00 [accepted] PHST- 2008/06/25 09:00 [pubmed] PHST- 2008/10/01 09:00 [medline] PHST- 2008/06/25 09:00 [entrez] AID - S0045-6535(08)00631-0 [pii] AID - 10.1016/j.chemosphere.2008.05.011 [doi] PST - ppublish SO - Chemosphere. 2008 Aug;72(10):1475-1480. doi: 10.1016/j.chemosphere.2008.05.011. Epub 2008 Jun 24.