PMID- 18653198 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20081110 LR - 20091111 IS - 1095-7103 (Electronic) IS - 0021-9797 (Linking) VI - 326 IP - 2 DP - 2008 Oct 15 TI - Superhydrophobic surface fabricated by bulk photografting of acrylic acid onto high-density polyethylene. PG - 360-5 LID - 10.1016/j.jcis.2008.06.023 [doi] AB - A superhydrophobic polymeric surface was prepared through a very simple bulk photografting method. A thin layer of acrylic acid (AA), a highly hydrophilic monomer, was sandwiched between two high-density polyethylene (HDPE) sheets, followed by UV irradiation for a short time, and then the two sheets were pulled apart and dried. The contact angles on the two grafted surfaces decreased very quickly with irradiation time in the first several seconds, and then increased with irradiation time to a level higher than that on pristine HDPE surface. When using a scraped PE surface as the bottom one, it showed superhydrophobicity after 35 s irradiation. XPS investigations show that strong rearrangement of the poly(acrylic acid) molecules has taken place on both surfaces, especially on the bottom surface, which provides the low surface free energy. The scraping and the grafting process led to the formation a unique micro- and nanostructure on the surface. These two factors lead to the superhydrophobicity. The as-prepared surface possesses superhydrophobic properties in a wide range of pH values, stimuli-responsive properties and low or very high adhesion under different situations. FAU - Han, Jianmei AU - Han J AD - College of Chemistry, Beijing Normal University, Beijing 100875, China. FAU - Wang, Xiaoxiao AU - Wang X FAU - Wang, Huiliang AU - Wang H LA - eng PT - Journal Article DEP - 20080618 PL - United States TA - J Colloid Interface Sci JT - Journal of colloid and interface science JID - 0043125 EDAT- 2008/07/26 09:00 MHDA- 2008/07/26 09:01 CRDT- 2008/07/26 09:00 PHST- 2008/03/21 00:00 [received] PHST- 2008/05/07 00:00 [revised] PHST- 2008/06/10 00:00 [accepted] PHST- 2008/07/26 09:00 [pubmed] PHST- 2008/07/26 09:01 [medline] PHST- 2008/07/26 09:00 [entrez] AID - S0021-9797(08)00763-7 [pii] AID - 10.1016/j.jcis.2008.06.023 [doi] PST - ppublish SO - J Colloid Interface Sci. 2008 Oct 15;326(2):360-5. doi: 10.1016/j.jcis.2008.06.023. Epub 2008 Jun 18.