PMID- 18762321 OWN - NLM STAT- MEDLINE DCOM- 20090122 LR - 20181201 IS - 0048-9697 (Print) IS - 0048-9697 (Linking) VI - 406 IP - 1-2 DP - 2008 Nov 15 TI - Increase of urban lake salinity by road deicing salt. PG - 131-44 LID - 10.1016/j.scitotenv.2008.07.037 [doi] AB - Over 317,000 tonnes of road salt (NaCl) are applied annually for road deicing in the Twin Cities Metropolitan Area (TCMA) of Minnesota. Although road salt is applied to increase driving safety, this practice influences environmental water quality. Thirteen lakes in the TCMA were studied over 46 months to determine if and how they respond to the seasonal applications of road salt. Sodium and chloride concentrations in these lakes were 10 and 25 times higher, respectively, than in other non-urban lakes in the region. Seasonal salinity/chloride cycles in the lakes were correlated with road salt applications: High concentrations in the winter and spring, especially near the bottom of the lakes, were followed by lower concentrations in the summer and fall due to flushing of the lakes by rainfall runoff. The seasonal salt storage/flushing rates for individual lakes were derived from volume-weighted average chloride concentration time series. The rate ranged from 9 to 55% of a lake's minimum salt content. In some of the lakes studied salt concentrations were high enough to stop spring turnover preventing oxygen from reaching the benthic sediments. Concentrations above the sediments were also high enough to induce convective mixing of the saline water into the sediment pore water. A regional analysis of historical water quality records of 38 lakes in the TCMA showed increases in lake salinity from 1984 to 2005 that were highly correlated with the amount of rock salt purchased by the State of Minnesota. Chloride concentrations in individual lakes were positively correlated with the percent of impervious surfaces in the watershed and inversely with lake volume. Taken together, the results show a continuing degradation of the water quality of urban lakes due to application of NaCl in their watersheds. FAU - Novotny, Eric V AU - Novotny EV AD - University of Minnesota, Department of Civil Engineering, St. Anthony Falls Laboratory, 2 Third Avenue SE, Minneapolis, MN 55414, 612-625-2810, USA. FAU - Murphy, Dan AU - Murphy D FAU - Stefan, Heinz G AU - Stefan HG LA - eng PT - Journal Article DEP - 20080831 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Ice) RN - 0 (Salts) RN - 0 (Water Pollutants, Chemical) SB - IM MH - *Cities MH - *Environmental Monitoring MH - Fresh Water/*chemistry MH - *Ice MH - Minnesota MH - Phase Transition MH - *Salinity MH - Salts/*analysis MH - Snow MH - Time Factors MH - Transportation MH - Water Movements MH - Water Pollutants, Chemical/*analysis EDAT- 2008/09/03 09:00 MHDA- 2009/01/23 09:00 CRDT- 2008/09/03 09:00 PHST- 2008/02/06 00:00 [received] PHST- 2008/07/14 00:00 [revised] PHST- 2008/07/15 00:00 [accepted] PHST- 2008/09/03 09:00 [pubmed] PHST- 2009/01/23 09:00 [medline] PHST- 2008/09/03 09:00 [entrez] AID - S0048-9697(08)00763-8 [pii] AID - 10.1016/j.scitotenv.2008.07.037 [doi] PST - ppublish SO - Sci Total Environ. 2008 Nov 15;406(1-2):131-44. doi: 10.1016/j.scitotenv.2008.07.037. Epub 2008 Aug 31.