PMID- 18956384
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20090122
LR  - 20081117
IS  - 1615-9314 (Electronic)
IS  - 1615-9306 (Linking)
VI  - 31
IP  - 21
DP  - 2008 Dec
TI  - Headspace single drop and hollow fiber liquid phase microextractions for HPLC 
      determination of phenols.
PG  - 3772-81
LID - 10.1002/jssc.200800365 [doi]
AB  - Two methods based on headspace single drop microextraction (HS-SDME) and 
      headspace hollow fiber liquid phase microextraction (HS-HF-LPME) were developed 
      and critically compared with HPLC-UV determination of phenols (including phenol 
      (Ph), 2-chlorophenol (CP), 2,4-dichlorophenol (DCP) and 2,4,6-trichlorophenol 
      (TCP)) in this paper. The significant parameters affecting the extraction 
      efficiency of the target analytes in both extraction modes were studied and the 
      optimal extraction conditions were established. Under the optimal conditions, the 
      detection limits (S/N = 3) for Ph, CP, DCP and TCP obtained by HS-SDME-HPLC-UV 
      and HS-HF-LPME-HPLC-UV were 2.1, 0.2, 0.8,1.1 ng/mL and 4.2, 0.4, 0.4, 0.4 ng/mL 
      with enrichment factors of 15.8, 198.9, 159.7, 194.8 and 9.2, 149.9, 301.9, 
      411.1, respectively. The RSDs obtained by HS-SDME-HPLC-UV and HS-HF-LPME-HPLC-UV 
      were 3.7, 4.0, 9.8, 6.7% and 6.3, 3.6, 3.1, 4.8% for Ph, CP, DCP and TCP, 
      respectively. Both extraction modes have a comparable analytical performance, but 
      HS-HF-LPME was more robust than HS-SDME, while HS-SDME was simpler than 
      HS-HF-LPME. The two headspace microextraction modes were applied for HPLC-UV 
      determination of target phenols in water, honey and toner samples, and the 
      determined values obtained by both techniques were in good agreement with each 
      other.
FAU - Wu, Yunli
AU  - Wu Y
AD  - Department of Chemistry, Wuhan University, Wuhan, China.
FAU - Hu, Bin
AU  - Hu B
FAU - Hou, Yanli
AU  - Hou Y
LA  - eng
PT  - Journal Article
PL  - Germany
TA  - J Sep Sci
JT  - Journal of separation science
JID - 101088554
EDAT- 2008/10/29 09:00
MHDA- 2008/10/29 09:01
CRDT- 2008/10/29 09:00
PHST- 2008/10/29 09:00 [pubmed]
PHST- 2008/10/29 09:01 [medline]
PHST- 2008/10/29 09:00 [entrez]
AID - 10.1002/jssc.200800365 [doi]
PST - ppublish
SO  - J Sep Sci. 2008 Dec;31(21):3772-81. doi: 10.1002/jssc.200800365.