PMID- 18966976 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20121002 LR - 20190729 IS - 0039-9140 (Print) IS - 0039-9140 (Linking) VI - 45 IP - 1 DP - 1997 Dec 12 TI - Highly sensitive colour-reaction of nickel with a new chromogenic reagent benzothiaxolyldiazoaminoazobenzene and its application. PG - 13-7 AB - The synthesis of benzothiaxolyldiazoaminoazobenzene (BTDAB) is described, and a simple, rapid and sensitive procedure for spectrophotometric determination of nickel has been developed. At pH 9.4, in the presence of emulsifier p-octylpolyethyleneglycol phenylether (OP), the reagent reacts with nickel to form a red 1:3 (metal:ligand) complex. The nickel-BTDAB complex exhibit an adsorption maximum at 550 nm with an apparent molar absorptivity of 1.96 x 10(5) 1 mol(-1) cm(-1), Beer's law is obeyed for nickel in the range 0-7 mug per 25 ml. The proposed method has been applied to the determination of nickel in aluminum alloy with satisfactory results. FAU - Zhao, S AU - Zhao S AD - Department of Polymer Chemical Engineering, Shenyang Institute of Chemical Technology, Shenyang, Liaoning 110021, China. FAU - Xia, X AU - Xia X FAU - Kong, X AU - Kong X FAU - Liu, T AU - Liu T LA - eng PT - Journal Article PL - Netherlands TA - Talanta JT - Talanta JID - 2984816R EDAT- 2008/10/31 09:00 MHDA- 2008/10/31 09:01 CRDT- 2008/10/31 09:00 PHST- 1996/08/30 00:00 [received] PHST- 1997/01/14 00:00 [revised] PHST- 1997/01/20 00:00 [accepted] PHST- 2008/10/31 09:00 [pubmed] PHST- 2008/10/31 09:01 [medline] PHST- 2008/10/31 09:00 [entrez] AID - S0039-9140(97)00030-1 [pii] AID - 10.1016/s0039-9140(97)00030-1 [doi] PST - ppublish SO - Talanta. 1997 Dec 12;45(1):13-7. doi: 10.1016/s0039-9140(97)00030-1.