PMID- 18970225
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20091214
LR  - 20081030
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 67
IP  - 4
DP  - 2005 Oct 15
TI  - Electroreduction of the antifouling agent TCMTB and its electroanalytical 
      determination in tannery wastewaters.
PG  - 682-5
LID - 10.1016/j.talanta.2005.01.058 [doi]
AB  - The electrochemical reduction of antifouling agent 
      2-thiocyanomethylthiobenzothiazole (TCMTB) was investigated by cyclic and pulse 
      differential voltammetry. The irreversible electrode reduction of TCMTB proceeded 
      by ECEC reaction mechanism by two electrons transfer with one irreversible wave. 
      Upon the basis of electrochemical evidence, the electrodic reaction mechanism was 
      suggested to formation of mercaptobenzothiazole (MTB) in solution. Subsequently, 
      a pulse differential method is described for the formation of TCMTB based on this 
      electroreduction. Having been obtained a detection limit of 1.0 x 10(-7)mol L(-1) 
      and recovery to 98% to concentration of 2.0 x 10(-6)mol L(-1). Therefore, the 
      proposed method in this study is practical, sensitive and accurate for the 
      analysis of TCMTB in tannery wastewater samples.
FAU - Meneses, Elaine S
AU  - Meneses ES
AD  - Laboratorio de Quimica Ambiental, Departamento de Quimica, Universidade Federal 
      de Sergipe, Sao Cristovao-SE, Brazil.
FAU - Arguelho, Maria Lara P M
AU  - Arguelho ML
FAU - Alves, Jose P H
AU  - Alves JP
LA  - eng
PT  - Journal Article
DEP - 20050622
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
EDAT- 2008/10/31 09:00
MHDA- 2008/10/31 09:01
CRDT- 2008/10/31 09:00
PHST- 2004/10/14 00:00 [received]
PHST- 2005/01/27 00:00 [revised]
PHST- 2005/01/27 00:00 [accepted]
PHST- 2008/10/31 09:00 [pubmed]
PHST- 2008/10/31 09:01 [medline]
PHST- 2008/10/31 09:00 [entrez]
AID - S0039-9140(05)00190-6 [pii]
AID - 10.1016/j.talanta.2005.01.058 [doi]
PST - ppublish
SO  - Talanta. 2005 Oct 15;67(4):682-5. doi: 10.1016/j.talanta.2005.01.058. Epub 2005 
      Jun 22.