PMID- 19073028
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20121002
LR  - 20081216
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 73
IP  - 2
DP  - 2007 Sep 15
TI  - Mesoporous titanium dioxide as a novel solid-phase extraction material for flow 
      injection micro-column preconcentration on-line coupled with ICP-OES 
      determination of trace metals in environmental samples.
PG  - 274-81
LID - 10.1016/j.talanta.2007.03.046 [doi]
AB  - Mesoporous titanium dioxide as a novel solid-phase extraction material for flow 
      injection micro-column preconcentration on-line coupled with ICP-OES 
      determination of trace metals (Co, Cd, Cr, Cu, Mn, Ni, V, Ce, Dy, Eu, La and Yb) 
      in environmental samples was described. Possessing a high adsorption capacity 
      towards the metal ions, mesoporous titanium dioxide has found to be of great 
      potential as an adsorbent for the preconcentration of trace metal ions in samples 
      with complicated matrix. The experimental parameters including pH, sample flow 
      rate, volume, elution and interfering ions on the recovery of the target analytes 
      were investigated, and the optimal experimental conditions were established. 
      Under the optimized operating conditions, a preconcentration time of 90s and 
      elution time of 18s with enrichment factor of 10 and sampling frequency of 
      20h(-1) were obtained. The detection limits of this method for the target 
      elements were between 0.03 and 0.36mugL(-1), and the relative standard deviations 
      (R.S.D.s) were found to be less than 6.0% (n=7, c=5ngmL(-1)). The proposed method 
      was validated using a certified reference material, and has been successfully 
      applied for the determination of the afore mentioned trace metals in natural 
      water samples and coal fly ash with satisfactory results.
FAU - Huang, Chaozhang
AU  - Huang C
AD  - Department of Chemistry, Wuhan University, Wuhan 430072, PR China.
FAU - Jiang, Zucheng
AU  - Jiang Z
FAU - Hu, Bin
AU  - Hu B
LA  - eng
PT  - Journal Article
DEP - 20070330
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
EDAT- 2007/09/15 00:00
MHDA- 2007/09/15 00:01
CRDT- 2008/12/17 09:00
PHST- 2006/11/17 00:00 [received]
PHST- 2007/03/17 00:00 [revised]
PHST- 2007/03/20 00:00 [accepted]
PHST- 2008/12/17 09:00 [entrez]
PHST- 2007/09/15 00:00 [pubmed]
PHST- 2007/09/15 00:01 [medline]
AID - S0039-9140(07)00231-7 [pii]
AID - 10.1016/j.talanta.2007.03.046 [doi]
PST - ppublish
SO  - Talanta. 2007 Sep 15;73(2):274-81. doi: 10.1016/j.talanta.2007.03.046. Epub 2007 
      Mar 30.