PMID- 19168180
OWN - NLM
STAT- MEDLINE
DCOM- 20090813
LR  - 20151119
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1216
IP  - 12
DP  - 2009 Mar 20
TI  - Solid-phase extraction combined with dispersive liquid-liquid microextraction for 
      the determination for polybrominated diphenyl ethers in different environmental 
      matrices.
PG  - 2220-6
LID - 10.1016/j.chroma.2008.12.092 [doi]
AB  - An analytical method, solid-phase extraction combined with dispersive 
      liquid-liquid microextration (SPE-DLLME), was established to determine 
      polybrominated diphenyl ethers (PBDEs) in water and plant samples. After 
      concentration and purification of the samples in LC-C18 column, 1.0-mL elution 
      sample containing 22.0 microL 1,1,2,2-tetrachloroethane was injected rapidly into 
      the 5.0-mL pure water. After extraction and centrifuging, the sedimented phase 
      was injected rapidly into gas chromatography with electron-capture detection 
      (GC-ECD). For water samples, enrichment factors (EFs) are in the range of 
      6838-9405 under the optimum conditions. The calibration curves are linear in the 
      range of 0.1-100 ng L(-1) (BDEs 28, 47) and 0.5-500 ng L(-1) (BDEs 100, 99, 85, 
      154, 153). The relative standard deviations (RSDs) and the limits of detection 
      (LODs) are in the range of 4.2-7.9% (n=5) and 0.03-0.15 ng L(-1), respectively. 
      For plant samples, RSDs and LODs are in the range of 5.9-11.3% and 0.04-0.16 
      microg kg(-1), respectively. The relative recoveries of well, river, sea, 
      leachate, and clover samples, spiked with different levels of PBDEs, are 
      66.8-94.1%, 72.2-100.5%, 74.5-110.4%, 62.1-105.1%, 66.1-91.7%, 62.4-88.9%, and 
      64.5-83.2%, respectively. The results show that SPE-DLLME is a suitable method 
      for the determination of PBDEs in water and plant samples.
FAU - Liu, Xiujuan
AU  - Liu X
AD  - Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Central 
      China Normal University, Wuhan, China. jtarrant@lortobco.com
FAU - Li, Jianwang
AU  - Li J
FAU - Zhao, Zhixu
AU  - Zhao Z
FAU - Zhang, Wei
AU  - Zhang W
FAU - Lin, Kuangfei
AU  - Lin K
FAU - Huang, Changjiang
AU  - Huang C
FAU - Wang, Xuedong
AU  - Wang X
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20090109
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Acetonitriles)
RN  - 0 (Halogenated Diphenyl Ethers)
RN  - 0 (Solvents)
RN  - 0 (Water Pollutants, Chemical)
RN  - 451W47IQ8X (Sodium Chloride)
SB  - IM
MH  - Acetonitriles/chemistry
MH  - Chromatography, Gas
MH  - Fresh Water/chemistry
MH  - Halogenated Diphenyl Ethers/*analysis
MH  - Medicago/chemistry
MH  - Osmolar Concentration
MH  - Reproducibility of Results
MH  - Seawater/chemistry
MH  - Sensitivity and Specificity
MH  - Sodium Chloride/chemistry
MH  - Solid Phase Extraction/*methods
MH  - Solvents/chemistry
MH  - Water Pollutants, Chemical/*analysis/chemistry
EDAT- 2009/01/27 09:00
MHDA- 2009/08/14 09:00
CRDT- 2009/01/27 09:00
PHST- 2008/10/17 00:00 [received]
PHST- 2008/12/16 00:00 [revised]
PHST- 2008/12/31 00:00 [accepted]
PHST- 2009/01/27 09:00 [entrez]
PHST- 2009/01/27 09:00 [pubmed]
PHST- 2009/08/14 09:00 [medline]
AID - S0021-9673(09)00018-1 [pii]
AID - 10.1016/j.chroma.2008.12.092 [doi]
PST - ppublish
SO  - J Chromatogr A. 2009 Mar 20;1216(12):2220-6. doi: 10.1016/j.chroma.2008.12.092. 
      Epub 2009 Jan 9.