PMID- 19256378 OWN - NLM STAT- MEDLINE DCOM- 20091027 LR - 20161018 IS - 0250-3301 (Print) IS - 0250-3301 (Linking) VI - 29 IP - 12 DP - 2008 Dec TI - [Ambient pressure synthesis and characterization of silica aerogel as adsorbent for dieldrin]. PG - 3415-20 AB - Hydrophobic silica aerogels were prepared from cheap waterglass precursors via surface modification of wet gels and ambient pressure drying route. Its adsorption capacity of Dieldrin, a typical of persistent organic pollutants (POPs), was examined. It is characterized via BET, FTIR, and DSC-TGA. The silica aerogels were highly hydrophobic with contact angles of 135 degrees-142 degrees, and the hydrophobicity of the aerogels could be maintained up to the temperature of 380 degrees C. The silica aerogels were porous with, pore size distribution of 17.5-23.4 nm, porosity of 94.8%-95.6%, and surface area of 444-560 m2 x g(-1). The results of adsorption experiments indicated that the hydrophobic aerogels could remove 84% of dieldrin from aqueous solution within 4 h; the adsorption process followed the pseudo-second-order kinetics process. Based on the adsorption equilibrium results, the adsorption capacity of silica aerogel was 11 times bigger than by active carbon. FAU - Sha, Wei AU - Sha W AD - State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. hewsay@gmail.com FAU - Liu, Rui-ping AU - Liu RP FAU - Liu, Hui-juan AU - Liu HJ FAU - Qu, Jiu-hui AU - Qu JH LA - chi PT - English Abstract PT - Journal Article PL - China TA - Huan Jing Ke Xue JT - Huan jing ke xue= Huanjing kexue JID - 8405344 RN - 0 (Gels) RN - 0 (Solvents) RN - 0 (Water Pollutants, Chemical) RN - 7631-86-9 (Silicon Dioxide) RN - I0246D2ZS0 (Dieldrin) SB - IM MH - Adsorption MH - Dieldrin/*isolation & purification MH - Gels MH - Hydrophobic and Hydrophilic Interactions MH - Pressure MH - Silicon Dioxide/*chemical synthesis/chemistry MH - Solvents/chemistry MH - Water Pollutants, Chemical/*chemistry MH - *Water Purification EDAT- 2009/03/05 09:00 MHDA- 2009/10/29 06:00 CRDT- 2009/03/05 09:00 PHST- 2009/03/05 09:00 [entrez] PHST- 2009/03/05 09:00 [pubmed] PHST- 2009/10/29 06:00 [medline] PST - ppublish SO - Huan Jing Ke Xue. 2008 Dec;29(12):3415-20.