PMID- 19260705 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20090626 LR - 20200930 IS - 1530-6992 (Electronic) IS - 1530-6984 (Linking) VI - 9 IP - 4 DP - 2009 Apr TI - Ex-MWNTs: graphene sheets and ribbons produced by lithium intercalation and exfoliation of carbon nanotubes. PG - 1527-33 LID - 10.1021/nl803585s [doi] AB - We found that multiwalled carbon nanotubes (MWNTs) can be opened longitudinally by intercalation of lithium and ammonia followed by exfoliation. Intercalation of open-ended tubes and exfoliation with acid treatment and abrupt heating provided the best results. The resulting material consists of: (i) multilayered flat graphitic structures (nanoribbons), (ii) partially open MWNTs, and (iii) graphene flakes. We called the completely unwrapped nanotubes ex-MWNTs, and their large number of edge atoms makes them attractive for many applications. FAU - Cano-Marquez, Abraham G AU - Cano-Marquez AG AD - Advanced Materials Department, Laboratory for Nanoscience and Nanotechnology Research, IPICYT, San Luis Potosi, SLP, Mexico. FAU - Rodriguez-Macias, Fernando J AU - Rodriguez-Macias FJ FAU - Campos-Delgado, Jessica AU - Campos-Delgado J FAU - Espinosa-Gonzalez, Claudia G AU - Espinosa-Gonzalez CG FAU - Tristan-Lopez, Ferdinando AU - Tristan-Lopez F FAU - Ramirez-Gonzalez, Daniel AU - Ramirez-Gonzalez D FAU - Cullen, David A AU - Cullen DA FAU - Smith, David J AU - Smith DJ FAU - Terrones, Mauricio AU - Terrones M FAU - Vega-Cantu, Yadira I AU - Vega-Cantu YI LA - eng PT - Journal Article PL - United States TA - Nano Lett JT - Nano letters JID - 101088070 EDAT- 2009/03/06 09:00 MHDA- 2009/03/06 09:01 CRDT- 2009/03/06 09:00 PHST- 2009/03/06 09:00 [entrez] PHST- 2009/03/06 09:00 [pubmed] PHST- 2009/03/06 09:01 [medline] AID - 10.1021/nl803585s [doi] PST - ppublish SO - Nano Lett. 2009 Apr;9(4):1527-33. doi: 10.1021/nl803585s.