PMID- 19378942
OWN - NLM
STAT- MEDLINE
DCOM- 20110524
LR  - 20110214
IS  - 1520-5118 (Electronic)
IS  - 0021-8561 (Linking)
VI  - 57
IP  - 10
DP  - 2009 May 27
TI  - Simultaneous extraction and cleanup method based on pressurized solvent 
      extraction for multiresidue analysis of pesticides in complex feed samples.
PG  - 3963-73
LID - 10.1021/jf9004252 [doi]
AB  - The development of a multiresidue method based on pressurized solvent extraction 
      (PSE) to determine a large number of pesticides (mostly pyrethroids and 
      organochlorines) in cattle feed is described. As far as we know, this is the 
      first work dedicated to the PSE of many of the target pesticides from animal 
      feed. A mixed level fraction design was performed to investigate the influence of 
      several operational variables on the PSE procedure; integrated cleanup strategies 
      were also assessed allowing the direct chromatographic analysis of the extracts. 
      Method accuracy was evaluated by the analysis of a certified reference material 
      (BCR-115) and different fortified cattle feed samples. Most analytes were 
      recovered in the range of 70-110%, with relative standard deviations generally 
      lower than 15%. Limits of detection (LODs) were below the maximum residue levels 
      (MRLs) set by the European Union for animal feed and main crops used in the 
      preparation of feedingstuffs. The applicability of the proposed method was 
      demonstrated by the analysis of real cattle feed samples collected from 23 dairy 
      farms located in Galicia (NW Spain).
FAU - Fernandez-Alvarez, Maria
AU  - Fernandez-Alvarez M
AD  - Departamento de Quimica Analitica, Nutricion y Bromatologia, Instituto de 
      Investigacion y Analisis Alimentario, Campus Sur, Universidad de Santiago de 
      Compostela, E-15782 Santiago de Compostela, Spain.
FAU - Llompart, Maria
AU  - Llompart M
FAU - Lamas, J Pablo
AU  - Lamas JP
FAU - Lores, Marta
AU  - Lores M
FAU - Garcia-Jares, Carmen
AU  - Garcia-Jares C
FAU - Garcia-Chao, Maria
AU  - Garcia-Chao M
FAU - Dagnac, Thierry
AU  - Dagnac T
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20090420
PL  - United States
TA  - J Agric Food Chem
JT  - Journal of agricultural and food chemistry
JID - 0374755
RN  - 0 (Acetamides)
RN  - 0 (Hydrocarbons, Chlorinated)
RN  - 0 (Organophosphorus Compounds)
RN  - 0 (Pesticide Residues)
RN  - 0 (Pyrethrins)
RN  - 0 (Solvents)
SB  - IM
MH  - Acetamides/analysis
MH  - Animal Feed/*analysis
MH  - Animals
MH  - Cattle
MH  - Chromatography, Gas
MH  - Food Analysis/*methods
MH  - Hydrocarbons, Chlorinated/analysis
MH  - Organophosphorus Compounds/analysis
MH  - Pesticide Residues/*analysis
MH  - Pressure
MH  - Pyrethrins/analysis
MH  - Solvents
EDAT- 2009/04/22 09:00
MHDA- 2011/05/25 06:00
CRDT- 2009/04/22 09:00
PHST- 2009/04/22 09:00 [entrez]
PHST- 2009/04/22 09:00 [pubmed]
PHST- 2011/05/25 06:00 [medline]
AID - 10.1021/jf9004252 [doi]
PST - ppublish
SO  - J Agric Food Chem. 2009 May 27;57(10):3963-73. doi: 10.1021/jf9004252. Epub 2009 
      Apr 20.