PMID- 19397293 OWN - NLM STAT- MEDLINE DCOM- 20100104 LR - 20091022 IS - 1936-086X (Electronic) IS - 1936-0851 (Linking) VI - 3 IP - 5 DP - 2009 May 26 TI - Functionalized few-walled carbon nanotubes for mechanical reinforcement of polymeric composites. PG - 1057-62 LID - 10.1021/nn9000512 [doi] AB - Compared to single-walled carbon nanotubes (SWNTs) and more defective multiwalled carbon nanotubes (MWNTs), the thin few-walled carbon nanotubes (FWNTs) are believed to have extraordinary mechanical properties. However, the enhancement of mechanical properties in FWNTs-polymer composites has remained elusive. In this study, free-standing carbon nanotubes (CNTs)/polymer composite films were fabricated with three types (SWNTs, FWNTs, MWNTs) of functionalized CNTs. The mechanical properties of composite films have been investigated. It is observed that the Young's modulus of composite films with only 0.2 wt % functionalized FWNTs shows a remarkable reinforcement value of dY/dV(f) = 1658 GPa, which is approximately 400 GPa higher than the highest value (dY/dV(f) = 1244 GPa) that was previously reported. In addition, the Young's modulus increased steadily with the increased concentration of FWNTs. The results indicated that FWNTs are practically the optimum reinforcing filler for the next generation of carbon nanotube-based composite materials. FAU - Hou, Ye AU - Hou Y AD - Department of Chemistry, Duke University, Durham, North Carolina 27708, USA. FAU - Tang, Jie AU - Tang J FAU - Zhang, Hongbo AU - Zhang H FAU - Qian, Cheng AU - Qian C FAU - Feng, Yiyu AU - Feng Y FAU - Liu, Jie AU - Liu J LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Research Support, U.S. Gov't, Non-P.H.S. PL - United States TA - ACS Nano JT - ACS nano JID - 101313589 RN - 0 (Macromolecular Substances) RN - 0 (Nanotubes, Carbon) RN - 0 (Polymers) SB - IM MH - Compressive Strength MH - Crystallization/*methods MH - Macromolecular Substances/chemistry MH - Manufactured Materials/analysis MH - Materials Testing MH - Molecular Conformation MH - Nanotechnology/*methods MH - Nanotubes, Carbon/*chemistry/*ultrastructure MH - Particle Size MH - Polymers/*chemistry MH - Stress, Mechanical MH - Surface Properties MH - Tensile Strength EDAT- 2009/04/29 09:00 MHDA- 2010/01/05 06:00 CRDT- 2009/04/29 09:00 PHST- 2009/04/29 09:00 [entrez] PHST- 2009/04/29 09:00 [pubmed] PHST- 2010/01/05 06:00 [medline] AID - 10.1021/nn9000512 [doi] PST - ppublish SO - ACS Nano. 2009 May 26;3(5):1057-62. doi: 10.1021/nn9000512.