PMID- 19484744 OWN - NLM STAT- MEDLINE DCOM- 20091005 LR - 20151119 IS - 1097-0274 (Electronic) IS - 0271-3586 (Linking) VI - 52 IP - 7 DP - 2009 Jul TI - Characterization of a fatal methyl bromide exposure by analysis of the water cooler. PG - 579-86 LID - 10.1002/ajim.20708 [doi] AB - BACKGROUND: A suspected inhalation exposure to methyl bromide (MeBr) in the packaging and shipping area of a chemical manufacturer resulted in a worker fatality and several symptomatic cases. However, air testing was negative for MeBr resulting in uncertainty regarding the potential chemical exposure. Methods of quickly confirming the exposure and magnitude were sought. METHODS: Head space air and water samples were obtained from the breakroom water cooler in the facility and tested for MeBr. RESULTS: Increased levels of MeBr were identified in the air and water samples from the cooler and used to calculate the MeBr concentration of air entering the cooler. The MeBr air concentration within the breakroom was estimated as 1,200-2,100 ppm depending on assumptions regarding the amount of water dispensed from the cooler both before and during the incident. CONCLUSIONS: Estimated MeBr air concentrations in the breakroom were consistent with those known to be associated with reported health effects among the involved workers. The water cooler analysis represented a unique method of retrospectively verifying and quantifying exposure to MeBr. FAU - Hewitt, David J AU - Hewitt DJ AD - Center for Toxicology and Environmental Health, LLC, North Little Rock, Arkansas 72118, USA. dhewitt@cteh.com FAU - Gandy, Jay AU - Gandy J LA - eng PT - Journal Article PL - United States TA - Am J Ind Med JT - American journal of industrial medicine JID - 8101110 RN - 0 (Air Pollutants, Occupational) RN - 0 (Hydrocarbons, Brominated) RN - 0 (Noxae) RN - 0 (Water Pollutants, Chemical) RN - 9V42E1Z7B6 (methyl bromide) SB - IM MH - Air Pollutants, Occupational/analysis/*poisoning MH - Chemical Industry MH - Dose-Response Relationship, Drug MH - Humans MH - Hydrocarbons, Brominated/analysis/chemical synthesis/*poisoning MH - Male MH - Noxae/analysis/chemical synthesis/*poisoning MH - Occupational Diseases/*chemically induced/mortality MH - Risk Factors MH - Water Pollutants, Chemical/analysis/*poisoning MH - Water Supply/*analysis EDAT- 2009/06/02 09:00 MHDA- 2009/10/06 06:00 CRDT- 2009/06/02 09:00 PHST- 2009/06/02 09:00 [entrez] PHST- 2009/06/02 09:00 [pubmed] PHST- 2009/10/06 06:00 [medline] AID - 10.1002/ajim.20708 [doi] PST - ppublish SO - Am J Ind Med. 2009 Jul;52(7):579-86. doi: 10.1002/ajim.20708.