PMID- 19647424 OWN - NLM STAT- MEDLINE DCOM- 20091201 LR - 20090915 IS - 1873-4235 (Electronic) IS - 0956-5663 (Linking) VI - 25 IP - 2 DP - 2009 Oct 15 TI - Selective recognition and removal of chlorophenols from aqueous solution using molecularly imprinted polymer prepared by reversible addition-fragmentation chain transfer polymerization. PG - 306-12 LID - 10.1016/j.bios.2009.07.001 [doi] AB - Molecularly imprinted polymer (MIP) for selective recognition and removal of chlorophenols from contaminated water was prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization using RAFT agent functionalized silica gel as the chain transfer agent. The prepared MIP nano-film hybrid silica gel (silica-MIP) was characterized using Fourier transform infrared spectrometer (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and BET adsorption isotherm analysis. The proper adsorption and selective recognition ability of the silica-MIP were studied by an equilibrium-adsorption method. The resulting silica-MIP showed outstanding affinity towards 2,4-dichlorophenol (2,4-DCP) in aqueous solution. The silica-MIP bind the original template 2,4-DCP with an appreciable selectivity over structurally related compounds, and the molecular recognition of 2,4-DCP was analyzed in detail. FAU - Li, Ying AU - Li Y AD - Department of Chemistry, Harbin Institute of Technology, Harbin 150090, China. FAU - Li, Xin AU - Li X FAU - Dong, Cunku AU - Dong C FAU - Li, Yuqi AU - Li Y FAU - Jin, Pengfei AU - Jin P FAU - Qi, Jingyao AU - Qi J LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20090717 PL - England TA - Biosens Bioelectron JT - Biosensors & bioelectronics JID - 9001289 RN - 0 (Chlorophenols) RN - 0 (Polymers) RN - 0 (Water Pollutants, Chemical) RN - 7631-86-9 (Silicon Dioxide) SB - IM MH - Biosensing Techniques/*methods MH - Chlorophenols/*analysis/*isolation & purification MH - Polymers/*chemistry MH - Silicon Dioxide/chemistry MH - Spectroscopy, Fourier Transform Infrared/*methods MH - Surface Properties MH - Water Pollutants, Chemical/*analysis MH - Water Purification/*methods EDAT- 2009/08/04 09:00 MHDA- 2009/12/16 06:00 CRDT- 2009/08/04 09:00 PHST- 2009/03/18 00:00 [received] PHST- 2009/07/02 00:00 [revised] PHST- 2009/07/09 00:00 [accepted] PHST- 2009/08/04 09:00 [entrez] PHST- 2009/08/04 09:00 [pubmed] PHST- 2009/12/16 06:00 [medline] AID - S0956-5663(09)00370-4 [pii] AID - 10.1016/j.bios.2009.07.001 [doi] PST - ppublish SO - Biosens Bioelectron. 2009 Oct 15;25(2):306-12. doi: 10.1016/j.bios.2009.07.001. Epub 2009 Jul 17.