PMID- 19809709 OWN - NLM STAT- MEDLINE DCOM- 20100118 LR - 20191210 IS - 1464-0333 (Electronic) IS - 1464-0325 (Linking) VI - 11 IP - 10 DP - 2009 Oct TI - Field calibration of polyurethane foam disk passive air samplers for PBDEs. PG - 1859-65 LID - 10.1039/b903152a [doi] AB - A field study was performed to derive uptake rates of airborne polybrominated diphenyl ethers (PBDEs) to polyurethane foam (PUF) disk passive air samplers (PAS) and to investigate the influence of deployment location and device design. Data are presented on the gas-particle partitioning of PBDEs, since atmospheric phase distribution was considered to be a variable which could affect sampler performance. Uptake rates for these compounds were similar to those derived previously for other classes of persistent organic pollutants (POPs) (approximately 2-6 m(3)/day), with rates higher for the higher brominated species. Whilst other compound classes (e.g. polychlorinated biphenyls) are predominantly present in the air in the gas phase, heavier PBDEs have an association with particulates in the atmosphere at ambient temperatures. In this study, the PUF disk PAS therefore sampled PBDEs present in the gas phase and on fine aerosols with a similar sampling efficiency to those which are predominantly gas phase compounds. Compounds which are exclusively on particles are sampled less efficiently. A comparison of the three most commonly used PUF deployment configurations, used by different research groups, indicated little difference in uptake rates. The ranges of derived air concentrations for BDE-47, -99, and -183 between three sampler designs were 7.5-9.8, 7.4-12.4, and 4.7-6.6 pg/m(3), respectively. This suggests the robustness of this sampler in comparisons between regional and global campaigns where these three designs are employed. FAU - Chaemfa, Chakra AU - Chaemfa C AD - Centre for Chemicals Management, Lancaster Environment Centre, Lancaster University, Lancaster, LA1 4YQ, UK. FAU - Barber, Jonathan L AU - Barber JL FAU - Moeckel, Claudia AU - Moeckel C FAU - Gocht, Tilman AU - Gocht T FAU - Harner, Tom AU - Harner T FAU - Holoubek, Ivan AU - Holoubek I FAU - Klanova, Jana AU - Klanova J FAU - Jones, Kevin C AU - Jones KC LA - eng PT - Evaluation Study PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20090720 PL - England TA - J Environ Monit JT - Journal of environmental monitoring : JEM JID - 100968688 RN - 0 (Aerosols) RN - 0 (Air Pollutants) RN - 0 (Halogenated Diphenyl Ethers) RN - 0 (Polyurethanes) SB - IM MH - Aerosols/*analysis/*chemistry MH - Air Pollutants/*analysis/chemistry MH - Calibration MH - Environmental Monitoring/instrumentation/*methods MH - Geography MH - Halogenated Diphenyl Ethers/*analysis MH - Particle Size MH - Polyurethanes/analysis MH - Temperature MH - Time Factors MH - Volatilization MH - Weather EDAT- 2009/10/08 06:00 MHDA- 2010/01/19 06:00 CRDT- 2009/10/08 06:00 PHST- 2009/10/08 06:00 [entrez] PHST- 2009/10/08 06:00 [pubmed] PHST- 2010/01/19 06:00 [medline] AID - 10.1039/b903152a [doi] PST - ppublish SO - J Environ Monit. 2009 Oct;11(10):1859-65. doi: 10.1039/b903152a. Epub 2009 Jul 20.