PMID- 19810728 OWN - NLM STAT- MEDLINE DCOM- 20100222 LR - 20200930 IS - 1530-6992 (Electronic) IS - 1530-6984 (Linking) VI - 9 IP - 12 DP - 2009 Dec TI - Incomplete exciton harvesting from fullerenes in bulk heterojunction solar cells. PG - 4037-41 LID - 10.1021/nl902205n [doi] AB - We investigate the internal quantum efficiencies (IQEs) of high efficiency poly-3-hexylthiophene:[6,6]-phenyl-C(61)-butyric acid methyl ester (P3HT:PCBM) solar cells and find them to be lower at wavelengths where the PCBM absorbs. Because the exciton diffusion length in PCBM is too small, excitons generated in PCBM decay before reaching the donor-acceptor interface. This result has implications for most state of the art organic solar cells, since all of the most efficient devices use fullerenes as electron acceptors. FAU - Burkhard, George F AU - Burkhard GF AD - Department of Applied Physics, Stanford University, Stanford, California 94305, USA. FAU - Hoke, Eric T AU - Hoke ET FAU - Scully, Shawn R AU - Scully SR FAU - McGehee, Michael D AU - McGehee MD LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Research Support, U.S. Gov't, Non-P.H.S. PL - United States TA - Nano Lett JT - Nano letters JID - 101088070 RN - 0 ((6,6)-phenyl C61-butyric acid methyl ester) RN - 0 (Fullerenes) RN - 0 (Organoselenium Compounds) RN - 0 (poly(3-hexyl)selenophene) SB - IM MH - *Electric Power Supplies MH - Equipment Design MH - Equipment Failure Analysis MH - Fullerenes/*chemistry/radiation effects MH - Light MH - Organoselenium Compounds/*chemistry/radiation effects MH - *Solar Energy EDAT- 2009/10/09 06:00 MHDA- 2010/02/23 06:00 CRDT- 2009/10/09 06:00 PHST- 2009/10/09 06:00 [entrez] PHST- 2009/10/09 06:00 [pubmed] PHST- 2010/02/23 06:00 [medline] AID - 10.1021/nl902205n [doi] PST - ppublish SO - Nano Lett. 2009 Dec;9(12):4037-41. doi: 10.1021/nl902205n.