PMID- 19878953
OWN - NLM
STAT- MEDLINE
DCOM- 20100419
LR  - 20191210
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1217
IP  - 7
DP  - 2010 Feb 12
TI  - Development of a method based on on-line reversed phase liquid chromatography and 
      gas chromatography coupled by means of an adsorption-desorption interface for the 
      analysis of selected chiral volatile compounds in methyl jasmonate treated 
      strawberries.
PG  - 1083-8
LID - 10.1016/j.chroma.2009.10.037 [doi]
AB  - A method based on the use of the through oven transfer adsorption-desorption 
      (TOTAD) interface in on-line coupling between reversed phase liquid 
      chromatography and gas chromatography (RPLC-GC) for the determination of chiral 
      volatile compounds was developed. In particular, the method was applied to the 
      study of the influence of methyl jasmonate (MJ) treatment on the production and 
      enantiomeric composition of selected aroma compounds in strawberry. The compounds 
      studied were ethyl 2-methylbutanoate, linalool and 
      4-hydroxy-2,5-dimethyl-3(2H)-furanone (i.e. furaneol), which were examined on 
      days 3, 6 and 9 after treatment. The method developed resulted in relative 
      standard deviations (RSDs) of 21.6%, 8.1% and 9.8% and limits of detection (LD) 
      of 0.04, 0.07 and 0.02mg/l for ethyl 2-methylbutanoate, linalool and furaneol, 
      respectively. The application of the RPLC-TOTAD-GC method allowed higher levels 
      of ethyl 2-methylbutanoate, linalool and furaneol to be detected, particularly 
      after 9 days of treatment. Besides, MJ demonstrated to affect the enantiomeric 
      distribution of ethyl 2-methylbutanoate. On the contrary, the enantiomeric 
      composition of linalool and furaneol kept constant in both control and MJ-treated 
      strawberries throughout the study. These results are discussed.
CI  - Copyright 2009 Elsevier B.V. All rights reserved.
FAU - de la Pena Moreno, Fernando
AU  - de la Pena Moreno F
AD  - Instituto de Fermentaciones Industriales, Consejo Superior de Investigaciones 
      Cientificas (CSIC), Juan de la Cierva 3, 28006 Madrid, Spain.
FAU - Blanch, Gracia Patricia
AU  - Blanch GP
FAU - Flores, Gema
AU  - Flores G
FAU - Ruiz Del Castillo, Maria Luisa
AU  - Ruiz Del Castillo ML
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20091020
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Acetates)
RN  - 0 (Acyclic Monoterpenes)
RN  - 0 (Butyrates)
RN  - 0 (Cyclopentanes)
RN  - 0 (Furans)
RN  - 0 (Monoterpenes)
RN  - 0 (Oxylipins)
RN  - 0 (Plant Growth Regulators)
RN  - 0 (Volatile Organic Compounds)
RN  - 3658-77-3 (furaneol)
RN  - 900N171A0F (methyl jasmonate)
RN  - D81QY6I88E (linalool)
SB  - IM
MH  - Acetates/*pharmacology
MH  - Acyclic Monoterpenes
MH  - Adsorption
MH  - Butyrates/analysis
MH  - Chromatography, Gas/*methods
MH  - Chromatography, Reverse-Phase/*methods
MH  - Cyclopentanes/*pharmacology
MH  - Fragaria/*chemistry/drug effects
MH  - Fruit/*chemistry/drug effects
MH  - Furans/analysis
MH  - Monoterpenes/analysis
MH  - Oxylipins/*pharmacology
MH  - Plant Growth Regulators/*pharmacology
MH  - Sensitivity and Specificity
MH  - Stereoisomerism
MH  - Volatile Organic Compounds/*analysis
EDAT- 2009/11/03 06:00
MHDA- 2010/04/20 06:00
CRDT- 2009/11/03 06:00
PHST- 2009/07/30 00:00 [received]
PHST- 2009/10/09 00:00 [revised]
PHST- 2009/10/12 00:00 [accepted]
PHST- 2009/11/03 06:00 [entrez]
PHST- 2009/11/03 06:00 [pubmed]
PHST- 2010/04/20 06:00 [medline]
AID - S0021-9673(09)01535-0 [pii]
AID - 10.1016/j.chroma.2009.10.037 [doi]
PST - ppublish
SO  - J Chromatogr A. 2010 Feb 12;1217(7):1083-8. doi: 10.1016/j.chroma.2009.10.037. 
      Epub 2009 Oct 20.