PMID- 20022623 OWN - NLM STAT- MEDLINE DCOM- 20100401 LR - 20100129 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 78 IP - 6 DP - 2010 Feb TI - Mass balance for POPs in hazardous and municipal solid waste incinerators. PG - 701-8 LID - 10.1016/j.chemosphere.2009.11.036 [doi] AB - The amount of different persistent organic pollutants (POPs) in the input of waste incinerators was compared to that in the output. Three cases were considered: a rotary kiln incinerating hazardous waste, a grate furnace incinerating municipal solid waste (MSW) and the same grate furnace co-incinerating plastics of waste of electrical and electronic equipment (WEEE) and automotive shredder residue (ASR) with MSW. The mass balance for PCBs in the rotary kiln indicates that these POPs are destroyed effectively during incineration. The grate furnace can be a sink or source of PCDD/Fs and PCBs depending on the concentrations in the incinerated waste. In order to compare the total amount of POPs in input and output, a methodology was developed whereby the amount of POPs was weighed according to minimal risk doses (MRDs) or cancer potency factors. For both incinerators the PCDD/Fs, PCBs and polyaromatic hydrocarbons (PAHs) are the main contributors to total weighed POP output. In MSW, the PCDD/Fs, PBDD/Fs and polybrominated diphenylethers (PBDEs) are the main contributors to the weighed POP input. The ratios of the weighed POP-input over -output clearly indicate that the rotary kiln incinerating hazardous waste is a weighed POP sink. The grate furnace incinerating MSW is a weighed POP sink or source depending on the POP-concentrations in the waste, but the difference between output and input is rather limited. When e.g. ASR and plastics of WEEE, containing high concentrations of PBDEs and PCBs, are co-incinerated in the grate furnace, it is clearly a weighed POP sink. CI - Copyright 2009 Elsevier Ltd. All rights reserved. FAU - Van Caneghem, J AU - Van Caneghem J AD - Department of Chemical Engineering, University of Leuven, De Croylaan 46, 3001 Heverlee, Belgium. jo.vancaneghem@cit.kuleuven.be FAU - Block, C AU - Block C FAU - Van Brecht, A AU - Van Brecht A FAU - Wauters, G AU - Wauters G FAU - Vandecasteele, C AU - Vandecasteele C LA - eng PT - Journal Article DEP - 20091222 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Environmental Pollutants) RN - 0 (Hazardous Waste) RN - 0 (Organic Chemicals) RN - 0 (Plastics) SB - IM MH - Electrical Equipment and Supplies MH - Environmental Pollutants/*analysis MH - Hazardous Waste/*analysis MH - Incineration/*instrumentation MH - Organic Chemicals/*analysis MH - Plastics EDAT- 2009/12/22 06:00 MHDA- 2010/04/02 06:00 CRDT- 2009/12/22 06:00 PHST- 2009/03/26 00:00 [received] PHST- 2009/11/24 00:00 [revised] PHST- 2009/11/25 00:00 [accepted] PHST- 2009/12/22 06:00 [entrez] PHST- 2009/12/22 06:00 [pubmed] PHST- 2010/04/02 06:00 [medline] AID - S0045-6535(09)01393-9 [pii] AID - 10.1016/j.chemosphere.2009.11.036 [doi] PST - ppublish SO - Chemosphere. 2010 Feb;78(6):701-8. doi: 10.1016/j.chemosphere.2009.11.036. Epub 2009 Dec 22.