PMID- 20152431
OWN - NLM
STAT- MEDLINE
DCOM- 20100518
LR  - 20191210
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 80
IP  - 5
DP  - 2010 Mar 15
TI  - Eggshell membrane-based solid-phase extraction combined with hydride generation 
      atomic fluorescence spectrometry for trace arsenic(V) in environmental water 
      samples.
PG  - 1907-12
LID - 10.1016/j.talanta.2009.10.042 [doi]
AB  - The eggshell membrane (ESM) contains several surface functional groups such as 
      amines, amides and carboxylic groups with potential as SPE adsorbent for the 
      retention of target species of interest. In this paper, the potential use of ESM, 
      a typical biomaterial, as solid-phase extraction (SPE) adsorbent is evaluated for 
      analysis of trace arsenic(V) in environmental water samples in combination with 
      hydride generation atomic fluorescence spectrometry (HG-AFS). In order to obtain 
      the satisfactory recovery of arsenic(V), various parameters including the 
      desorption and enrichment conditions such as pH, the flow rate and the volume of 
      sample solution, the amount of ESM and the content of sodium chloride were 
      systematically optimized and the effects of co-existed ions were also 
      investigated in detail. Under the optimal conditions, arsenic(V) could be easily 
      extracted by the ESM packed cartridge and the breakthrough adsorption capacity 
      was found to be 3.9 microg g(-1). The favorable limit of detection (LOD) for 
      arsenic(V) was found to be 0.001 microg L(-1) with an enrichment factor of 33.3, 
      and the relative standard deviations (R.S.Ds) was 2.1% for 0.6 microg L(-1) 
      arsenic (n=11). The reproducibility among columns was satisfactory (R.S.D. among 
      columns is less than 5%). The proposed method has been successfully applied to 
      analysis of arsenic(V) in aqueous environmental samples, which suggests the ESM 
      can be an excellent SPE adsorbent for arsenic(V) pretreatment and enrichment from 
      real water samples.
CI  - Copyright (c) 2009 Elsevier B.V. All rights reserved.
FAU - Zhang, Yongjiang
AU  - Zhang Y
AD  - The Key Laboratory of Luminescence and Realtime Analysis, Ministry of Education, 
      College of Chemistry and Chemical Engineering, Southwest University, No 2 Road 
      Tiansheng, Beibei, Chongqing 400715, China.
FAU - Wang, Weidong
AU  - Wang W
FAU - Li, Lu
AU  - Li L
FAU - Huang, Yuming
AU  - Huang Y
FAU - Cao, Jia
AU  - Cao J
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20091024
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - N712M78A8G (Arsenic)
SB  - IM
MH  - Adsorption
MH  - Animals
MH  - Arsenic/analysis/*isolation & purification
MH  - Chickens
MH  - *Egg Shell/anatomy & histology
MH  - Fresh Water/*analysis
MH  - Limit of Detection
MH  - Membranes/*chemistry
MH  - Solid Phase Extraction/*methods
EDAT- 2010/02/16 06:00
MHDA- 2010/05/19 06:00
CRDT- 2010/02/16 06:00
PHST- 2009/07/27 00:00 [received]
PHST- 2009/10/13 00:00 [revised]
PHST- 2009/10/18 00:00 [accepted]
PHST- 2010/02/16 06:00 [entrez]
PHST- 2010/02/16 06:00 [pubmed]
PHST- 2010/05/19 06:00 [medline]
AID - S0039-9140(09)00831-5 [pii]
AID - 10.1016/j.talanta.2009.10.042 [doi]
PST - ppublish
SO  - Talanta. 2010 Mar 15;80(5):1907-12. doi: 10.1016/j.talanta.2009.10.042. Epub 2009 
      Oct 24.