PMID- 20208121 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20100609 LR - 20100317 IS - 1361-6528 (Electronic) IS - 0957-4484 (Linking) VI - 21 IP - 13 DP - 2010 Apr 2 TI - Extremely high aspect ratio GaAs and GaAs/AlGaAs nanowaveguides fabricated using chlorine ICP etching with N2-promoted passivation. PG - 134014 LID - 10.1088/0957-4484/21/13/134014 [doi] AB - Semiconductor nanowaveguides are the key structure for light-guiding nanophotonics applications. Efficient guiding and confinement of single-mode light in these waveguides require high aspect ratio geometries. In these conditions, sidewall verticality becomes crucial. We fabricated such structures using a top-down process combining electron beam lithography and inductively coupled plasma (ICP) etching of hard masks and GaAs/AlGaAs semiconductors with Al concentrations varying from 0 to 100%. The GaAs/AlGaAs plasma etching was a single-step process using a Cl(2)/BCl(3)/Ar gas mixture with various fractions of N(2). Scanning electron microscope (SEM) observations showed that the presence of nitrogen generated the deposition of a passivation layer, which had a significant effect on sidewall slope. Near-ideal vertical sidewalls were obtained over a very narrow range of N(2), allowing the production of extremely high aspect ratios (>32) for 80 nm wide nanowaveguides. FAU - Volatier, Maite AU - Volatier M AD - Centre de Recherche en Nanofabrication et en Nanocaracterisation (CRN2), Universite de Sherbrooke, Sherbrooke, QC, Canada. FAU - Duchesne, David AU - Duchesne D FAU - Morandotti, Roberto AU - Morandotti R FAU - Ares, Richard AU - Ares R FAU - Aimez, Vincent AU - Aimez V LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20100308 PL - England TA - Nanotechnology JT - Nanotechnology JID - 101241272 EDAT- 2010/03/09 06:00 MHDA- 2010/03/09 06:01 CRDT- 2010/03/09 06:00 PHST- 2010/03/09 06:00 [entrez] PHST- 2010/03/09 06:00 [pubmed] PHST- 2010/03/09 06:01 [medline] AID - S0957-4484(10)30129-2 [pii] AID - 10.1088/0957-4484/21/13/134014 [doi] PST - ppublish SO - Nanotechnology. 2010 Apr 2;21(13):134014. doi: 10.1088/0957-4484/21/13/134014. Epub 2010 Mar 8.