PMID- 20334354 OWN - NLM STAT- MEDLINE DCOM- 20100715 LR - 20200930 IS - 1530-6992 (Electronic) IS - 1530-6984 (Linking) VI - 10 IP - 4 DP - 2010 Apr 14 TI - 20 micros photocurrent response from lithographically patterned nanocrystalline cadmium selenide nanowires. PG - 1481-5 LID - 10.1021/nl100483v [doi] AB - Lithographically patterned nanowire electrodeposition (LPNE) provides a method for patterning nanowires composed of nanocrystalline cadmium selenide (nc-CdSe) over wafer-scale areas. We assess the properties of (nc-CdSe) nanowires for detecting light as photoconductors. Structural characterization of these nanowires by X-ray diffraction and transmission electron microscopy reveals they are composed of stoichiometric, single phase, cubic CdSe with a mean grain diameter of 10 nm. For nc-CdSe nanowires with lengths of many millimeters, the width and height dimensions could be varied over the range from 60 to 350 nm (w) and 20 to 80 nm (h). Optical absorption and photoluminescence spectra for nc-CdSe nanowires were both dominated by band-edge transitions. The photoconductivity properties of nc-CdSe nanowire arrays containing approximately 350 nanowires were evaluated by electrically isolating 5 microm nanowire lengths using evaporated gold electrodes. Photocurrents, i(photo), of 10-100 x (i(dark)) were observed with a spectral response characterized by an onset at 1.75 eV. i(photo) response and recovery times were virtually identical and in the range from 20 to 40 micros for 60 x 200 nm nanowires. FAU - Kung, Sheng-Chin AU - Kung SC AD - Department of Chemistry, University of California, Irvine, California 92697-2025, USA. FAU - van der Veer, Wytze E AU - van der Veer WE FAU - Yang, Fan AU - Yang F FAU - Donavan, Keith C AU - Donavan KC FAU - Penner, Reginald M AU - Penner RM LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Research Support, U.S. Gov't, Non-P.H.S. PL - United States TA - Nano Lett JT - Nano letters JID - 101088070 RN - 0 (Cadmium Compounds) RN - 0 (Selenium Compounds) RN - 7440-57-5 (Gold) RN - A7F646JC5C (cadmium selenide) SB - IM MH - Cadmium Compounds/*chemistry MH - Electrochemistry MH - Electrodes MH - Gold/chemistry MH - Light MH - Nanotechnology/*methods MH - Nanowires/*chemistry MH - Particle Size MH - Photochemistry MH - Selenium Compounds/*chemistry MH - Surface Properties EDAT- 2010/03/26 06:00 MHDA- 2010/07/16 06:00 CRDT- 2010/03/26 06:00 PHST- 2010/03/26 06:00 [entrez] PHST- 2010/03/26 06:00 [pubmed] PHST- 2010/07/16 06:00 [medline] AID - 10.1021/nl100483v [doi] PST - ppublish SO - Nano Lett. 2010 Apr 14;10(4):1481-5. doi: 10.1021/nl100483v.