PMID- 20336013 OWN - NLM STAT- MEDLINE DCOM- 20100810 LR - 20211020 IS - 1420-3049 (Electronic) IS - 1420-3049 (Linking) VI - 15 IP - 3 DP - 2010 Mar 12 TI - Synthesis and characterization of organotin containing copolymers: reactivity ratio studies. PG - 1784-97 LID - 10.3390/molecules15031784 [doi] AB - Organotin monomers containing dibutyltin groups--dibutyltin citraconate (DBTC) as a new monomer and dibutyltin maleate (DBTM)--were synthesized. Free radical copolymerizations of the organotin monomers with styrene (ST) and butyl acrylate (BA) were performed. The overall conversion was kept low (< or = 15% wt/wt) for all studied samples and the copolymers composition was determined from tin analysis using the Gillman and Rosenberg method. The reactivity ratios were calculated from the copolymer composition using the Fineman-Ross (FR) method. The synthesized monomers were characterized by elemental analysis, 1H-, 13C-NMR and FTIR spectroscopy. FAU - Al-Deyab, Salem S AU - Al-Deyab SS AD - Chemistry Department, College of Science, King Saud University, Riyadh 11451, P.O. Box 2455, Saudi Arabia. ssdeyab@ksu.edu.sa FAU - Al-Hazmi, Ali Mohsen AU - Al-Hazmi AM FAU - El-Newehy, Mohamed H AU - El-Newehy MH LA - eng PT - Journal Article DEP - 20100312 PL - Switzerland TA - Molecules JT - Molecules (Basel, Switzerland) JID - 100964009 RN - 0 (Organotin Compounds) RN - 0 (Polymers) SB - IM MH - Magnetic Resonance Spectroscopy MH - Organotin Compounds/*chemical synthesis/chemistry MH - Polymers/*chemistry MH - Spectroscopy, Fourier Transform Infrared PMC - PMC6257311 EDAT- 2010/03/26 06:00 MHDA- 2010/08/11 06:00 PMCR- 2010/03/12 CRDT- 2010/03/26 06:00 PHST- 2010/01/25 00:00 [received] PHST- 2010/02/20 00:00 [revised] PHST- 2010/03/08 00:00 [accepted] PHST- 2010/03/26 06:00 [entrez] PHST- 2010/03/26 06:00 [pubmed] PHST- 2010/08/11 06:00 [medline] PHST- 2010/03/12 00:00 [pmc-release] AID - 15031784 [pii] AID - molecules-15-01784 [pii] AID - 10.3390/molecules15031784 [doi] PST - epublish SO - Molecules. 2010 Mar 12;15(3):1784-97. doi: 10.3390/molecules15031784.