PMID- 20394939
OWN - NLM
STAT- MEDLINE
DCOM- 20100728
LR  - 20161125
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1217
IP  - 22
DP  - 2010 May 28
TI  - Fast preparation of photopolymerized poly(benzyl methacrylate-co-bisphenol A 
      dimethacrylate) monoliths for capillary electrochromatography.
PG  - 3628-34
LID - 10.1016/j.chroma.2010.03.043 [doi]
AB  - A novel porous polymer monolith was prepared in situ in a fused-silica capillary 
      using photoinitiated polymerization. Bisphenol A dimethacrylate (BPADMA) was 
      selected as a crosslinker, copolymerized with benzyl methacrylate (BMA) in the 
      presence of a binary porogenic solvent consisting of cyclohexanol and 1-decanol 
      in < or =10 min. The resulting poly(BMA-co-BPADMA) monoliths exhibited good 
      permeability and mechanical stability. Mixtures of alkylbenzenes, polycyclic 
      aromatic hydrocarbons (PAHs) or phenolic compounds were successfully separated by 
      CEC. A similar monolith was also prepared with ethylene dimethacrylate (EDMA) as 
      the crosslinker instead of BPADMA to compare the separation ability of the 
      resulting monoliths. The results indicated that poly(BMA-co-BPADMA) monoliths 
      have better selectivity for aromatic analytes and greater chromatographic 
      stability in higher aqueous mobile phase.
CI  - Copyright 2010 Elsevier B.V. All rights reserved.
FAU - Ou, Junjie
AU  - Ou J
AD  - Department of Chemistry, Queen's University, Kingston, Ontario K7L 3N6, Canada.
FAU - Gibson, Graham T T
AU  - Gibson GT
FAU - Oleschuk, Richard D
AU  - Oleschuk RD
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20100330
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Acetonitriles)
RN  - 0 (Benzene Derivatives)
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Methacrylates)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (Polymethacrylic Acids)
RN  - 0 (polybenzylmethacrylate)
RN  - 7BK5G69305 (ethylene dimethacrylate)
RN  - 982O8255NE (2,2-di(4-methacryloxyphenyl)propane)
RN  - Z072SB282N (acetonitrile)
SB  - IM
MH  - Acetonitriles
MH  - Benzene Derivatives
MH  - Benzhydryl Compounds
MH  - Capillary Electrochromatography/*methods
MH  - Methacrylates/chemical synthesis/*chemistry
MH  - Microscopy, Electron, Scanning
MH  - Permeability
MH  - Polycyclic Aromatic Hydrocarbons/analysis
MH  - Polymethacrylic Acids/chemical synthesis/*chemistry
MH  - Porosity
MH  - Pressure
EDAT- 2010/04/17 06:00
MHDA- 2010/07/29 06:00
CRDT- 2010/04/17 06:00
PHST- 2009/12/01 00:00 [received]
PHST- 2010/03/17 00:00 [revised]
PHST- 2010/03/24 00:00 [accepted]
PHST- 2010/04/17 06:00 [entrez]
PHST- 2010/04/17 06:00 [pubmed]
PHST- 2010/07/29 06:00 [medline]
AID - S0021-9673(10)00426-7 [pii]
AID - 10.1016/j.chroma.2010.03.043 [doi]
PST - ppublish
SO  - J Chromatogr A. 2010 May 28;1217(22):3628-34. doi: 10.1016/j.chroma.2010.03.043. 
      Epub 2010 Mar 30.