PMID- 20398942 OWN - NLM STAT- MEDLINE DCOM- 20100820 LR - 20131121 IS - 1873-3344 (Electronic) IS - 0162-0134 (Linking) VI - 104 IP - 7 DP - 2010 Jul TI - DNA assisted fragmentation of nickel nanoparticle clusters and their spectral properties. PG - 712-7 LID - 10.1016/j.jinorgbio.2010.03.003 [doi] AB - Nickel nanoparticle (NiNP) clusters in the range of 60-70 nm size on interaction with herring-sperm DNA (B-DNA) form a self-assembled duplex helix DNA structure with fragmented NiNPs as small as 5-15 nm, as evident from atomic force microscopic studies. Scanning electron microscope (SEM) and transmission electron microscope (TEM) images also corroborate the findings. The properties of these self-assembled NiNPs-DNA structures have been further investigated by UV-visible, emission and circular dichroic (CD) spectral studies. CI - 2010 Elsevier Inc. All rights reserved. FAU - Prabakaran, Natarajan AU - Prabakaran N AD - Department of Inorganic Chemistry, Madurai Kamaraj University, Madurai-625 021, India. FAU - Athappan, Periakaruppan AU - Athappan P LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20100320 PL - United States TA - J Inorg Biochem JT - Journal of inorganic biochemistry JID - 7905788 RN - 7OV03QG267 (Nickel) RN - 9007-49-2 (DNA) SB - IM MH - DNA/*chemistry/metabolism MH - Metal Nanoparticles/*chemistry MH - Microscopy, Atomic Force MH - Microscopy, Electron MH - Molecular Structure MH - Nickel/*chemistry MH - Nucleic Acid Conformation MH - Particle Size MH - Spectrum Analysis EDAT- 2010/04/20 06:00 MHDA- 2010/08/21 06:00 CRDT- 2010/04/20 06:00 PHST- 2009/12/25 00:00 [received] PHST- 2010/02/26 00:00 [revised] PHST- 2010/03/12 00:00 [accepted] PHST- 2010/04/20 06:00 [entrez] PHST- 2010/04/20 06:00 [pubmed] PHST- 2010/08/21 06:00 [medline] AID - S0162-0134(10)00066-8 [pii] AID - 10.1016/j.jinorgbio.2010.03.003 [doi] PST - ppublish SO - J Inorg Biochem. 2010 Jul;104(7):712-7. doi: 10.1016/j.jinorgbio.2010.03.003. Epub 2010 Mar 20.