PMID- 20550169
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20100929
LR  - 20100630
IS  - 1520-6882 (Electronic)
IS  - 0003-2700 (Linking)
VI  - 82
IP  - 13
DP  - 2010 Jul 1
TI  - Enhanced solid-state electrochemiluminescence of 
      tris(2,2'-bipyridyl)ruthenium(II) incorporated into electrospun nanofibrous mat.
PG  - 5892-6
LID - 10.1021/ac100435z [doi]
AB  - An electrospun poly(acrylonitrile-co-acrylic acid) nanofiber mat 
      (PAN-co-PAA(nfm)) was successfully collected on the surface of a glassy carbon 
      electrode (GCE). Scanning electron microscope (SEM) images showed that the porous 
      electrospun mat was composed of approximately 160 nm diameter of uniform knitted 
      nanofibers. The cationic luminescence probe, tris(2,2'-bipyridyl)ruthenium(II) 
      complex ([Ru(bpy)(3)](2+)), was innovatively and first incorporated into the 
      negatively charged PAN-co-PAA(nfm)-modified GCE via electrostatic interaction. 
      Compared with the [Ru(bpy)(3)](2+) immobilized on normal PAN-co-PAA deposited 
      coating, [Ru(bpy)(3)](2+)/PAN-co-PAA(nfm) exhibited dramatically enhanced 
      electrochemical and electrochemiluminescence (ECL) performances, namely, more 
      than 100 times higher ECL intensity could be feasibly obtained via the 
      electrospinning technique.
FAU - Shan, Dan
AU  - Shan D
AD  - Key Laboratory of Environmental Materials & Environmental Engineering of Jiangsu 
      Province, College of Chemistry & Chemical Engineering, Yangzhou University, 
      Yangzhou 225002, China. danshan@yzu.edu.cn
FAU - Qian, Bo
AU  - Qian B
FAU - Ding, Shou-Nian
AU  - Ding SN
FAU - Zhu, Wei
AU  - Zhu W
FAU - Cosnier, Serge
AU  - Cosnier S
FAU - Xue, Huai-Guo
AU  - Xue HG
LA  - eng
PT  - Journal Article
PL  - United States
TA  - Anal Chem
JT  - Analytical chemistry
JID - 0370536
EDAT- 2010/06/17 06:00
MHDA- 2010/06/17 06:01
CRDT- 2010/06/17 06:00
PHST- 2010/06/17 06:00 [entrez]
PHST- 2010/06/17 06:00 [pubmed]
PHST- 2010/06/17 06:01 [medline]
AID - 10.1021/ac100435z [doi]
PST - ppublish
SO  - Anal Chem. 2010 Jul 1;82(13):5892-6. doi: 10.1021/ac100435z.