PMID- 20631949
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20101028
LR  - 20100715
IS  - 1477-9234 (Electronic)
IS  - 1477-9226 (Linking)
VI  - 39
IP  - 29
DP  - 2010 Aug 7
TI  - Syntheses and structures of bora-amidinate lanthanide(III) complexes.
PG  - 6677-81
LID - 10.1039/c001966f [doi]
AB  - The use and coordination modes of the dianionic bora-amidinate ligand in 
      lanthanide(III) chemistry is explored. Synthetic routes to complexes of the type 
      (DIPP)NBN-LnR (Ln = lanthanide, (DIPP)NBN = HB[N(2,6-iPr(2)-phenyl)](2), R = an 
      amide or benzylide group) have been developed. The reaction of (DIPP)NBN-H(2) 
      with (DMA)(3)Sm (DMA = 2-Me(2)N-benzyl) gave dark-red crystals of 
      (DIPP)NBN-Sm(DMA) in 68% yield. The yttrium analogue, (DIPP)NBN-Y(DMA), was 
      prepared similarly (yellow crystals, 58% yield). The reaction of 
      (DIPP)NBN-Sm(DMA) with (Me(3)Si)(2)NH gave (DIPP)NBN-SmN(SiMe(3))(2).(THF)(2) 
      (yellow crystals, 54% yield). Crystal structure determinations of 
      (DIPP)NBN-Sm(DMA) and (DIPP)NBN-Y(DMA) revealed dimeric complexes that are held 
      together by LnDIPP interactions. The complex (DIPP)NBN-SmN(SiMe(3))(2).(THF)(2) 
      crystallized as a monomer. NMR investigations of [(DIPP)NBN-Y(DMA)](2) in benzene 
      indicate that it is also dimeric in solution. The addition of THF resulted in its 
      dissociation into monomeric units of (DIPP)NBN-Y(DMA).(THF)(x).
FAU - Harder, Sjoerd
AU  - Harder S
AD  - Anorganische Chemie, Universitat Duisburg-Essen, Universitatsstrasse 5, 45117, 
      Essen, Germany. sjoerd.harder@uni-due.de
LA  - eng
PT  - Journal Article
DEP - 20100325
PL  - England
TA  - Dalton Trans
JT  - Dalton transactions (Cambridge, England : 2003)
JID - 101176026
EDAT- 2010/07/16 06:00
MHDA- 2010/07/16 06:01
CRDT- 2010/07/16 06:00
PHST- 2010/07/16 06:00 [entrez]
PHST- 2010/07/16 06:00 [pubmed]
PHST- 2010/07/16 06:01 [medline]
AID - 10.1039/c001966f [doi]
PST - ppublish
SO  - Dalton Trans. 2010 Aug 7;39(29):6677-81. doi: 10.1039/c001966f. Epub 2010 Mar 25.