PMID- 20712336 OWN - NLM STAT- MEDLINE DCOM- 20101221 LR - 20131121 IS - 1944-8244 (Print) IS - 1944-8244 (Linking) VI - 2 IP - 9 DP - 2010 Sep TI - UV/thermally driven rewritable wettability patterns on TiO2-PDMS composite films. PG - 2485-8 LID - 10.1021/am1005207 [doi] AB - Composite films of TiO2 and polydimethylsiloxane (PDMS) are prepared by a sol-gel method, cured with UV irradiation, and then treated in hot water to crystallize the TiO2 in the film. The presence of anatase TiO2 contributes to the photoinduced superhydrophilicity of the film under UV irradiation. Contact angle studies reveal that the TiO2-PDMS composite film recovers its original hydrophobic state. Hydrophobic-superhydrophilic patterns are successfully formed on the films. The wettability patterns can be erased by UV irradiation and thermal treatment. New wettability patterns can be reconstructed, demonstrating that the film exhibits rewritable wettability without the need for organic chemicals. FAU - Nakata, Kazuya AU - Nakata K AD - Photocatalyst Group, Kanagawa Academy of Science and Technology, KSP Building West 614, 3-2-1 Sakado, Takatsu-ku, Kawasaki, Kanagawa 213-0012, Japan. FAU - Kimura, Hiroaki AU - Kimura H FAU - Sakai, Munetoshi AU - Sakai M FAU - Ochiai, Tsuyoshi AU - Ochiai T FAU - Sakai, Hideki AU - Sakai H FAU - Murakami, Taketoshi AU - Murakami T FAU - Abe, Masahiko AU - Abe M FAU - Fujishima, Akira AU - Fujishima A LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - United States TA - ACS Appl Mater Interfaces JT - ACS applied materials & interfaces JID - 101504991 RN - 0 (Dimethylpolysiloxanes) RN - 0 (Membranes, Artificial) RN - 0 (Nylons) RN - 0 (poly(dimethylsiloxane)-polyamide copolymer) RN - 15FIX9V2JP (titanium dioxide) RN - D1JT611TNE (Titanium) SB - IM MH - Dimethylpolysiloxanes/*chemistry/*radiation effects MH - Hot Temperature MH - Materials Testing MH - *Membranes, Artificial MH - Nylons/*chemistry/*radiation effects MH - Photochemistry/*methods MH - Surface Properties/radiation effects MH - Titanium/*chemistry/*radiation effects MH - Ultraviolet Rays MH - Wettability/*radiation effects EDAT- 2010/08/18 06:00 MHDA- 2010/12/22 06:00 CRDT- 2010/08/18 06:00 PHST- 2010/08/18 06:00 [entrez] PHST- 2010/08/18 06:00 [pubmed] PHST- 2010/12/22 06:00 [medline] AID - 10.1021/am1005207 [doi] PST - ppublish SO - ACS Appl Mater Interfaces. 2010 Sep;2(9):2485-8. doi: 10.1021/am1005207.