PMID- 20727785
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20110203
LR  - 20211020
IS  - 1879-1123 (Electronic)
IS  - 1044-0305 (Linking)
VI  - 21
IP  - 11
DP  - 2010 Nov
TI  - Dioxin analysis by gas chromatography-Fourier transform ion cyclotron resonance 
      mass spectrometry (GC-FTICRMS).
PG  - 1918-21
LID - 10.1016/j.jasms.2010.07.010 [doi]
AB  - The feasibility of utilizing a gas chromatograph-tandem quadrupole-Fourier 
      transform ion cyclotron resonance mass spectrometer (GC-MS/MS-FTICRMS) to analyze 
      chlorinated-dioxins/furans (CDDs/CDFs) and mixed halogenated dioxins/furans 
      (HDDs/HDFs) was investigated by operating the system in the GC-FTICRMS mode. 
      CDDs/CDFs and mixed HDDs/HDFs could be analyzed at 50,000 to 100,000 resolving 
      power (RP) on the capillary gas chromatographic time scale. Initial experiments 
      demonstrated that 1 pg of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) and 5 pg of 
      2-bromo-3,7,8-trichlorodibenzo-p-dioxin (BTrCDD) could be detected. The 
      feasibility of utilizing an FTICRMS for screening of CDDs/CDFs, HDDs/HDFs and 
      related compounds was also investigated by analyzing an extract from vegetation 
      exposed to fall-out from an industrial fire. CDDs/CDFs, chlorinated pyrenes and 
      chlorinated tetracenes could be detected from a Kendrick plot analysis of the 
      ultrahigh resolution mass spectra. Mass accuracies were of the order of 0.5 ppm 
      on standards with external mass calibration and 1 ppm on a sample with internal 
      mass calibration.
CI  - Copyright (c) 2010 American Society for Mass Spectrometry. Published by Elsevier 
      Inc. All rights reserved.
FAU - Taguchi, Vince Y
AU  - Taguchi VY
AD  - Ontario Ministry of the Environment, Toronto, Ontario, Canada. 
      vince.taguchi@ontario.ca
FAU - Nieckarz, Robert J
AU  - Nieckarz RJ
FAU - Clement, Ray E
AU  - Clement RE
FAU - Krolik, Stefan
AU  - Krolik S
FAU - Williams, Robert
AU  - Williams R
LA  - eng
PT  - Journal Article
DEP - 20100802
PL  - United States
TA  - J Am Soc Mass Spectrom
JT  - Journal of the American Society for Mass Spectrometry
JID - 9010412
EDAT- 2010/08/24 06:00
MHDA- 2010/08/24 06:01
CRDT- 2010/08/24 06:00
PHST- 2010/04/23 00:00 [received]
PHST- 2010/07/27 00:00 [revised]
PHST- 2010/07/29 00:00 [accepted]
PHST- 2010/08/24 06:00 [entrez]
PHST- 2010/08/24 06:00 [pubmed]
PHST- 2010/08/24 06:01 [medline]
AID - S1044-0305(10)00511-8 [pii]
AID - 10.1016/j.jasms.2010.07.010 [doi]
PST - ppublish
SO  - J Am Soc Mass Spectrom. 2010 Nov;21(11):1918-21. doi: 
      10.1016/j.jasms.2010.07.010. Epub 2010 Aug 2.