PMID- 20800853 OWN - NLM STAT- MEDLINE DCOM- 20110114 LR - 20161125 IS - 1879-3363 (Electronic) IS - 0025-326X (Linking) VI - 60 IP - 11 DP - 2010 Nov TI - Organic pollutants in microplastics from two beaches of the Portuguese coast. PG - 1988-92 LID - 10.1016/j.marpolbul.2010.07.030 [doi] AB - Microplastics pose a threat to coastal environments due to their capacity to adsorb persistent organic pollutants (POPs). These particles (less than 5 mm in size) are potentially dangerous to marine species due to magnification risk over the food chain. Samples were collected from two Portuguese beaches and sorted in four classes to relate the adsorption capacity of pollutants with color and age. Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and DDTs were analysed on pellets through gas chromatography mass spectrometry (GC-MS), and types of plastic were identified using Fourier transformed infra-red spectroscopy (micro-FTIR). Microplastics were mostly polyethylene and polypropylene. Regarding sizes, some fibres ranged from 1 to 5 mum in diameter and were 500 mum in length. The majority of samples collected had sizes above 200 mum. Black pellets, unlike aged pellets, had the highest concentrations of POPs except for PAHs in Fonte da Telha beach. PAHs with higher concentrations were pyrene, phenantrene, chrysene and fluoranthene. Higher concentrations of PCBs were found for congeners 18, 31, 138 and 187. Further investigation is necessary to understand the relationship between plastic degradation and adsorption for different pollutants. CI - Copyright (c) 2010 Elsevier Ltd. All rights reserved. FAU - Frias, J P G L AU - Frias JP AD - IMAR-Instituto do Mar, Departamento de Ciencias e Engenharia do Ambiente, Faculdade de Ciencias e Tecnologia da Universidade Nova de Lisboa, 2829-516 Monte de Caparica, Portugal. jpfrias@fct.unl.pt FAU - Sobral, P AU - Sobral P FAU - Ferreira, A M AU - Ferreira AM LA - eng PT - Journal Article DEP - 20100830 PL - England TA - Mar Pollut Bull JT - Marine pollution bulletin JID - 0260231 RN - 0 (Environmental Pollutants) RN - 0 (Plastics) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - CIW5S16655 (DDT) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Adsorption MH - DDT/analysis MH - Environmental Monitoring MH - Environmental Pollutants/*analysis MH - Geologic Sediments MH - Plastics/*chemistry MH - Polychlorinated Biphenyls/*analysis MH - Polycyclic Aromatic Hydrocarbons/*analysis MH - Portugal EDAT- 2010/08/31 06:00 MHDA- 2011/01/15 06:00 CRDT- 2010/08/31 06:00 PHST- 2010/05/17 00:00 [received] PHST- 2010/07/19 00:00 [revised] PHST- 2010/07/23 00:00 [accepted] PHST- 2010/08/31 06:00 [entrez] PHST- 2010/08/31 06:00 [pubmed] PHST- 2011/01/15 06:00 [medline] AID - S0025-326X(10)00336-X [pii] AID - 10.1016/j.marpolbul.2010.07.030 [doi] PST - ppublish SO - Mar Pollut Bull. 2010 Nov;60(11):1988-92. doi: 10.1016/j.marpolbul.2010.07.030. Epub 2010 Aug 30.