PMID- 20947127 OWN - NLM STAT- MEDLINE DCOM- 20101223 LR - 20101124 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 82 IP - 1 DP - 2011 Jan TI - Organochlorine pesticide residues in sediments from the Uganda side of Lake Victoria. PG - 130-6 LID - 10.1016/j.chemosphere.2010.09.010 [doi] AB - Organochlorine (OC) residues were analysed in 117 sediment samples collected from four bays of the Uganda side of Lake Victoria. The sediments were collected with a corer at a depth of 0-20 cm, and extracted for OC residues using a solid dispersion method. The extracts were cleaned using gel permeation chromatography and analysed for pesticide residues using a gas chromatograph (GC) equipped with an electron capture detector. The results were confirmed using a GC equipped with a mass spectrometer (MS). A total of 16 OC residues, most of them persistent organic pollutants (POPs) were identified and quantified. The OC residue levels were expressed on an oven dry weight (d.w.) basis. Endosulphan sulphate, in the range of 0.82-5.62 mug kg(-)(1) d.w., was the most frequently detected residue. Aldrin and dieldrin were in the ranges of 0.22-15.96 and 0.94-7.18 mug kg(-)(1) d.w., respectively. DDT and its metabolites lay between 0.11-3.59 for p,p'-DDE, 0.38-4.02 for p,p'-DDD, 0.04-1.46 for p,p'-DDT, 0.07-2.72 for o,p'-DDE and 0.01-1.63 mug kg(-)(1) d.w. for o,p'-DDT. The levels of gamma-HCH varied from 0.05 to 5.48 mug kg(-)(1) d.w. Heptachlor was detected only once at a level of 0.81 mug kg(-)(1) d.w., while its photo-oxidation product, heptachlor epoxide, ranged between non-detectable (ND) to 3.19 mug kg(-)(1) d.w. Chlordane ranged from ND to 0.76 mug kg(-)(1) d.w. Based on the threshold effect concentration (TEC) for fresh water ecosystems, aldrin and dieldrin were the only OCs that seemed to be a threat to the lake environment. CI - Copyright (c) 2010 Elsevier Ltd. All rights reserved. FAU - Wasswa, John AU - Wasswa J AD - Department of Chemistry, Makerere University, Kampala, Uganda. jnwasswa@chemistry.mak.ac.ug FAU - Kiremire, Bernard T AU - Kiremire BT FAU - Nkedi-Kizza, Peter AU - Nkedi-Kizza P FAU - Mbabazi, Jolocam AU - Mbabazi J FAU - Ssebugere, Patrick AU - Ssebugere P LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20101013 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticide Residues) RN - 0 (Water Pollutants, Chemical) SB - IM MH - Environmental Monitoring MH - Fresh Water/*chemistry MH - Geologic Sediments/*chemistry MH - Hydrocarbons, Chlorinated/*analysis MH - Pesticide Residues/*analysis MH - Uganda MH - Water Pollutants, Chemical/*analysis MH - Water Pollution, Chemical/statistics & numerical data EDAT- 2010/10/16 06:00 MHDA- 2010/12/25 06:00 CRDT- 2010/10/16 06:00 PHST- 2010/03/26 00:00 [received] PHST- 2010/07/15 00:00 [revised] PHST- 2010/09/02 00:00 [accepted] PHST- 2010/10/16 06:00 [entrez] PHST- 2010/10/16 06:00 [pubmed] PHST- 2010/12/25 06:00 [medline] AID - S0045-6535(10)01007-6 [pii] AID - 10.1016/j.chemosphere.2010.09.010 [doi] PST - ppublish SO - Chemosphere. 2011 Jan;82(1):130-6. doi: 10.1016/j.chemosphere.2010.09.010. Epub 2010 Oct 13.