PMID- 21046791
OWN - NLM
STAT- MEDLINE
DCOM- 20120213
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 28
IP  - 7
DP  - 2010 Jul
TI  - [Simultaneous determination of ammonium and six alkylamines in cosmetics by ion 
      chromatography].
PG  - 702-7
AB  - A method for the simultaneous determination of ammonium and six alkylamines in 
      cosmetic products by ion chromatography (IC) was developed. The sample 
      pretreatment process and the separation resolution of chromatography were 
      investigated. The samples were extracted by 100 mmol/L acetic acid-20% (v/v) 
      acetonitrile solution at room temperature, and then solid phase extraction (SPE) 
      column was used to eliminate the interferences. The influences of pH value, 
      organic solvent and coexisted ions were investigated. The separation was carried 
      out on IonPac CS17 (250 mm x 4 mm)analytical column and IonPac CG17 (50 mm x 4 
      mm)guard column using 1.5 - 15 mmol/L methanesulfonic acid and 0.5% - 5% (v/v) 
      acetonitrile gradient elution at a flow rate of 1.0 mL/min at 24 degrees C, 
      coupled with suppressed conductivity detector. Under the optimum conditions, a 
      measurement could be completed less than 26 min. The linearity ranged from 0.3 to 
      15 mg/L, the detection limits and the quantification limits were in the ranges of 
      2.1 - 7.9 mg/kg and 7 - 26 mg/kg, respectively. The method was successfully 
      employed for the determination of ammonium, methylamine, dimethylamine, 
      trimethylamine, ethylamine, propylamine and butylamine in samples including 
      cleaning, body lotion, skin-bleaching, sun block, marcel, hair dye and pilatory 
      cosmetics with the recoveries of 80.2% - 109.2% and the relative standard 
      deviations (RSDs) of 0.5% - 3.1%. The method offered high selectivity, 
      sensitivity, and gave satisfactory results for real sample analysis.
FAU - Zhong, Zhixiong
AU  - Zhong Z
AD  - Center for Disease Control and Prevention of Guangdong Province, Guangzhou 
      510300, China. zzxiong608@yahoo.com.cn
FAU - Li, Gongke
AU  - Li G
FAU - Zhu, Binghui
AU  - Zhu B
FAU - Luo, Zhibin
AU  - Luo Z
FAU - Wu, Ximei
AU  - Wu X
LA  - chi
PT  - English Abstract
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Alkadienes)
RN  - 0 (Amines)
RN  - 0 (Cosmetics)
RN  - 0 (Methylamines)
RN  - 0 (Quaternary Ammonium Compounds)
SB  - IM
MH  - Alkadienes/analysis
MH  - Alkylation
MH  - Amines/*analysis
MH  - Chromatography, Ion Exchange/*methods
MH  - Cosmetics/*analysis
MH  - Methylamines/*analysis
MH  - Quaternary Ammonium Compounds/*analysis
MH  - Sensitivity and Specificity
EDAT- 2010/11/05 06:00
MHDA- 2012/02/14 06:00
CRDT- 2010/11/05 06:00
PHST- 2010/11/05 06:00 [entrez]
PHST- 2010/11/05 06:00 [pubmed]
PHST- 2012/02/14 06:00 [medline]
AID - 10.3724/sp.j.1123.2010.00702 [doi]
PST - ppublish
SO  - Se Pu. 2010 Jul;28(7):702-7. doi: 10.3724/sp.j.1123.2010.00702.