PMID- 21084097 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20110421 LR - 20110103 IS - 1095-7103 (Electronic) IS - 0021-9797 (Linking) VI - 354 IP - 2 DP - 2011 Feb 15 TI - Synthesis and physical properties of new surfactants based on ionic liquids: Improvement of thermal stability and mechanical behaviour of high density polyethylene nanocomposites. PG - 555-62 LID - 10.1016/j.jcis.2010.10.058 [doi] AB - Ionic liquids based on alkyltriphenyl phosphonium and dialkyl imidazolium cations with long alkyl chains have been synthesized and used as new surfactants for cationic exchange of layered silicates. The influence of the alkyl chain length and the chemical nature of the conteranion or of the cation on the thermal stability of these new intercalating agents and on imidazolium- (MMT-I) or phosphonium- (MMT-P) modified montmorillonites have been analyzed by thermogravimetric analysis (TGA). Thermoplastic nanocomposites based on these modified montmorillonites with a very low amount of nanofillers (1wt.%) have been processed by melt mixing using a twin screw extruder. The distribution of the clay layers in a high density polyethylene (HDPE) matrix was characterized and finally the mechanical and thermal properties of the corresponding nanocomposites were determined. CI - Copyright A(c) 2010 Elsevier Inc. All rights reserved. FAU - Livi, Sebastien AU - Livi S AD - Universite de Lyon, F-69003, Lyon, France. sebastien.livi@gmail.com FAU - Duchet-Rumeau, Jannick AU - Duchet-Rumeau J FAU - Pham, Thi Nhan AU - Pham TN FAU - Gerard, Jean-Francois AU - Gerard JF LA - eng PT - Journal Article DEP - 20101030 PL - United States TA - J Colloid Interface Sci JT - Journal of colloid and interface science JID - 0043125 EDAT- 2010/11/19 06:00 MHDA- 2010/11/19 06:01 CRDT- 2010/11/19 06:00 PHST- 2010/09/14 00:00 [received] PHST- 2010/10/25 00:00 [revised] PHST- 2010/10/26 00:00 [accepted] PHST- 2010/11/19 06:00 [entrez] PHST- 2010/11/19 06:00 [pubmed] PHST- 2010/11/19 06:01 [medline] AID - S0021-9797(10)01244-0 [pii] AID - 10.1016/j.jcis.2010.10.058 [doi] PST - ppublish SO - J Colloid Interface Sci. 2011 Feb 15;354(2):555-62. doi: 10.1016/j.jcis.2010.10.058. Epub 2010 Oct 30.