PMID- 21185028
OWN - NLM
STAT- MEDLINE
DCOM- 20110421
LR  - 20151119
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1218
IP  - 3
DP  - 2011 Jan 21
TI  - Electrochemical preparation of polyaniline-ionic liquid based solid phase 
      microextraction fiber and its application in the determination of benzene 
      derivatives.
PG  - 387-91
LID - 10.1016/j.chroma.2010.12.017 [doi]
AB  - A polyaniline-ionic liquid (i.e. 1-butyl-3-methylimidazolium tetrafluoroborate, 
      [C(4)mim][BF(4)]) composite film coated platinum wire (PANI-IL/Pt) was prepared 
      by electrochemical method for the first time. Scanning electron microscopy image 
      showed that the PANI-IL composite film was even and porous. When the PANI-IL/Pt 
      was used as a fiber for the headspace solid-phase microextraction (HS-SPME) of 
      some benzene derivatives (i.e. 1,3-dimethylbenzene, 1,2-dimethylbenzene, 
      1,4-dichlorobenzene, 1,2-dichlorobenzene, 1,3,5-trimethylbenzene and 
      1,2,4-trimethylbenzene), followed by gas chromatographic analysis, it presented 
      excellent performance, which was much better than that of PANI/Pt and commercial 
      polydimethylsiloxane fiber. Hence the fiber was coupled with gas chromatography 
      for the determination of these benzene derivatives. It was found that under the 
      optimized conditions the linear ranges were 0.04-400 mug L(-1) with correlation 
      coefficients above 0.99, the detection limits were 9.3-48.1 ng L(-1) (S/N=3), the 
      relative standard deviations (RSDs) were smaller than 5.1% for five successive 
      measurements with single fiber, and the RSDs for fiber-to-fiber were 5.0-11.1% 
      (n=3) for different benzene derivatives. The proposed method was successfully 
      applied to the extraction and determination of benzene derivatives in waste water 
      and tap water, and the recoveries were 87.1-108.1% for different analytes. 
      Therefore, the PANI-IL/Pt is a promising SPME fiber.
CI  - Copyright A(c) 2010 Elsevier B.V. All rights reserved.
FAU - Zhao, Faqiong
AU  - Zhao F
AD  - College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, 
      Hubei, China. fqzhao@whu.edu.cn
FAU - Wang, Meili
AU  - Wang M
FAU - Ma, Yuyu
AU  - Ma Y
FAU - Zeng, Baizhao
AU  - Zeng B
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20101213
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (1-butyl-3-methylimidazolium tetrafluoroborate)
RN  - 0 (Aniline Compounds)
RN  - 0 (Benzene Derivatives)
RN  - 0 (Imidazoles)
RN  - 0 (Ionic Liquids)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (polyaniline)
RN  - 451W47IQ8X (Sodium Chloride)
RN  - 49DFR088MY (Platinum)
SB  - IM
MH  - Aniline Compounds/*chemistry
MH  - Benzene Derivatives/analysis/*isolation & purification
MH  - Chromatography, Liquid
MH  - Drug Stability
MH  - Electrochemical Techniques
MH  - Imidazoles/chemistry
MH  - Ionic Liquids/*chemistry
MH  - Microscopy, Electron, Scanning
MH  - Platinum/chemistry
MH  - Reproducibility of Results
MH  - Sodium Chloride/chemistry
MH  - Solid Phase Microextraction/instrumentation/*methods
MH  - Temperature
MH  - Time Factors
MH  - Water Pollutants, Chemical/analysis/*isolation & purification
EDAT- 2010/12/28 06:00
MHDA- 2011/04/22 06:00
CRDT- 2010/12/28 06:00
PHST- 2010/10/07 00:00 [received]
PHST- 2010/11/27 00:00 [revised]
PHST- 2010/12/07 00:00 [accepted]
PHST- 2010/12/28 06:00 [entrez]
PHST- 2010/12/28 06:00 [pubmed]
PHST- 2011/04/22 06:00 [medline]
AID - S0021-9673(10)01693-6 [pii]
AID - 10.1016/j.chroma.2010.12.017 [doi]
PST - ppublish
SO  - J Chromatogr A. 2011 Jan 21;1218(3):387-91. doi: 10.1016/j.chroma.2010.12.017. 
      Epub 2010 Dec 13.