PMID- 21254398
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20110503
LR  - 20110207
IS  - 1615-9314 (Electronic)
IS  - 1615-9306 (Linking)
VI  - 34
IP  - 4
DP  - 2011 Feb
TI  - Supramolecular-based dispersive liquid-liquid microextraction: a novel sample 
      preparation technique utilizes coacervates and reverse micelles.
PG  - 455-61
LID - 10.1002/jssc.201000630 [doi]
AB  - The present study reports a novel sample enrichment method termed 
      supramolecular-based dispersive liquid-liquid microextraction (SM-DLLME). The SM 
      solvent selected was made up of reversed micelles of decanoic acid dispersed in 
      tetrahydrofuran (THF)-water. THF plays double role, not only acts as a disperser 
      solvent but also causes self-assembly of decanoic acid. The contaminant used as a 
      model was Malachite Green (MG). It was a cationic dye and was preconcentrated 
      without any derivatization or ion-pair formation reaction. In SM-DLLME, the most 
      important advantages of DLLME technique and preconcentration strategy based on 
      the coacervation and reverse micelles have come together. Moreover, in this 
      method, disadvantages of DLLME such as extraction capability of only hydrophobic 
      analytes and hiring toxic and hazardous organic solvents as the extraction 
      solvent and disadvantages of coacervation-based extraction method such as 
      tedious, labor-intensive and time-consuming stirring procedure have been avoided. 
      Several variables affecting the microextraction efficiency were investigated and 
      optimized. Under the optimized conditions and preconcentration of only 5.00 mL of 
      sample, the enhancement factor was 52, limit of detection (LOD) was 4 mug/L and 
      relative standard deviations (RSDs) for 145 and 36 mug/L of MG in textile industry 
      wastewater were 1.8 and 3.2%, respectively (n = 6).
CI  - Copyright (c) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Jafarvand, Sanaz
AU  - Jafarvand S
AD  - Department of Analytical Chemistry, Faculty of Chemistry, University College of 
      Science, University of Tehran, Tehran, Iran.
FAU - Shemirani, Farzaneh
AU  - Shemirani F
LA  - eng
PT  - Journal Article
DEP - 20110120
PL  - Germany
TA  - J Sep Sci
JT  - Journal of separation science
JID - 101088554
EDAT- 2011/01/22 06:00
MHDA- 2011/01/22 06:01
CRDT- 2011/01/22 06:00
PHST- 2010/08/29 00:00 [received]
PHST- 2010/11/30 00:00 [revised]
PHST- 2010/11/30 00:00 [accepted]
PHST- 2011/01/22 06:00 [entrez]
PHST- 2011/01/22 06:00 [pubmed]
PHST- 2011/01/22 06:01 [medline]
AID - 10.1002/jssc.201000630 [doi]
PST - ppublish
SO  - J Sep Sci. 2011 Feb;34(4):455-61. doi: 10.1002/jssc.201000630. Epub 2011 Jan 20.