PMID- 21386504 OWN - NLM STAT- MEDLINE DCOM- 20110817 LR - 20110309 IS - 1361-648X (Electronic) IS - 0953-8984 (Linking) VI - 22 IP - 33 DP - 2010 Aug 25 TI - Intrinsic doping and gate hysteresis in graphene field effect devices fabricated on SiO2 substrates. PG - 334214 LID - 10.1088/0953-8984/22/33/334214 [doi] AB - We have studied the intrinsic doping level and gate hysteresis of graphene-based field effect transistors (FETs) fabricated over Si/SiO(2) substrates. It was found that the high p-doping level of graphene in some as-prepared devices can be reversed by vacuum degassing at room temperature or above depending on the degree of hydrophobicity and/or hydration of the underlying SiO(2) substrate. Charge neutrality point (CNP) hysteresis, consisting of the shift of the charge neutrality point (or Dirac peak) upon reversal of the gate voltage sweep direction, was also greatly reduced upon vacuum degassing. However, another type of hysteresis, consisting of the change in the transconductance upon reversal of the gate voltage sweep direction, persists even after long-term vacuum annealing at 200 degrees C, when SiO(2) surface-bound water is expected to be desorbed. We propose a mechanism for this transconductance hysteresis that involves water-related defects, formed during the hydration of the near-surface silanol groups in the bulk SiO(2), that can act as electron traps. FAU - Joshi, P AU - Joshi P AD - Department of Electrical Engineering, The Pennsylvania State University, University Park, PA 16802, USA. FAU - Romero, H E AU - Romero HE FAU - Neal, A T AU - Neal AT FAU - Toutam, V K AU - Toutam VK FAU - Tadigadapa, S A AU - Tadigadapa SA LA - eng PT - Journal Article PT - Research Support, U.S. Gov't, Non-P.H.S. DEP - 20100804 PL - England TA - J Phys Condens Matter JT - Journal of physics. Condensed matter : an Institute of Physics journal JID - 101165248 RN - 7631-86-9 (Silicon Dioxide) SB - IM MH - Equipment Design MH - Equipment Failure Analysis MH - Materials Testing MH - Nanostructures/*chemistry/*ultrastructure MH - Nanotechnology/*instrumentation MH - Particle Size MH - Silicon Dioxide/*chemistry MH - *Transistors, Electronic EDAT- 2011/03/10 06:00 MHDA- 2011/08/19 06:00 CRDT- 2011/03/10 06:00 PHST- 2011/03/10 06:00 [entrez] PHST- 2011/03/10 06:00 [pubmed] PHST- 2011/08/19 06:00 [medline] AID - S0953-8984(10)44083-7 [pii] AID - 10.1088/0953-8984/22/33/334214 [doi] PST - ppublish SO - J Phys Condens Matter. 2010 Aug 25;22(33):334214. doi: 10.1088/0953-8984/22/33/334214. Epub 2010 Aug 4.