PMID- 21454935 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20110725 LR - 20110405 IS - 1361-6528 (Electronic) IS - 0957-4484 (Linking) VI - 22 IP - 22 DP - 2011 Jun 3 TI - An aqueous solution-based doping strategy for large-scale synthesis of Sb-doped ZnO nanowires. PG - 225602 LID - 10.1088/0957-4484/22/22/225602 [doi] AB - An aqueous solution-based doping strategy was developed for controlled doping impurity atoms into a ZnO nanowire (NW) lattice. Through this approach, antimony-doped ZnO NWs were successfully synthesized in an aqueous solution containing zinc nitrate and hexamethylenetetramine with antimony acetate as the dopant source. By introducing glycolate ions into the solution, a soluble antimony precursor (antimony glycolate) was formed and a good NW morphology with a controlled antimony doping concentration was successfully achieved. A doping concentration study suggested an antimony glycolate absorption doping mechanism. By fabricating and characterizing NW-based field effect transistors (FETs), stable p-type conductivity was observed. A field effect mobility of 1.2 cm(2) V(-1) s(-1) and a carrier concentration of 6 x 10(17) cm(-3) were achieved. Electrostatic force microscopy (EFM) characterization on doped and undoped ZnO NWs further illustrated the shift of the metal-semiconductor barrier due to Sb doping. This work provided an effective large-scale synthesis strategy for doping ZnO NWs in aqueous solution. FAU - Wang, Fei AU - Wang F AD - Department of Materials Science and Engineering, University of Wisconsin, Madison, Wisconsin, USA. FAU - Seo, Jung-Hun AU - Seo JH FAU - Bayerl, Dylan AU - Bayerl D FAU - Shi, Jian AU - Shi J FAU - Mi, Hongyi AU - Mi H FAU - Ma, Zhenqiang AU - Ma Z FAU - Zhao, Deyin AU - Zhao D FAU - Shuai, Yichen AU - Shuai Y FAU - Zhou, Weidong AU - Zhou W FAU - Wang, Xudong AU - Wang X LA - eng PT - Journal Article PT - Research Support, U.S. Gov't, Non-P.H.S. DEP - 20110401 PL - England TA - Nanotechnology JT - Nanotechnology JID - 101241272 EDAT- 2011/04/02 06:00 MHDA- 2011/04/02 06:01 CRDT- 2011/04/02 06:00 PHST- 2011/04/02 06:00 [entrez] PHST- 2011/04/02 06:00 [pubmed] PHST- 2011/04/02 06:01 [medline] AID - S0957-4484(11)79747-1 [pii] AID - 10.1088/0957-4484/22/22/225602 [doi] PST - ppublish SO - Nanotechnology. 2011 Jun 3;22(22):225602. doi: 10.1088/0957-4484/22/22/225602. Epub 2011 Apr 1.