PMID- 21543830 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20110930 LR - 20110505 IS - 1361-6528 (Electronic) IS - 0957-4484 (Linking) VI - 22 IP - 24 DP - 2011 Jun 17 TI - Piperidine induced polarity conversion in single-walled carbon nanotube field effect transistors. PG - 245306 LID - 10.1088/0957-4484/22/24/245306 [doi] AB - Piperidine is found to be an efficient electron doping agent that converts as-prepared p-type single-walled carbon nanotube (SWCNT) field effect transistors (FETs) into n-type SWCNT-FETs. Electron transfer from the amine group in piperidine to the SWCNTs is suggested to be the origin of the p- to n-type conversion. The effect of electron doping is further supported by the Raman tangential G(+) and G(-)-peak downshift up to 3 cm(-1) without the peak broadening. No detectable change in the Raman D-peak suggests non-covalent attachment of piperidine to the SWCNTs. A low temperature (110 degrees C) Si(3)N(4) passivation layer is used to maintain the long term air stability of the converted n-type devices. A complementary SWCNT inverter is demonstrated through integrating the n- and p-type SWCNT-FETs. FAU - Raj, Kumar AU - Raj K AD - Microelectronics Centre, School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore. FAU - Zhang, Qing AU - Zhang Q FAU - Liu, Chao AU - Liu C FAU - Park, Mary B Chan AU - Park MB LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20110504 PL - England TA - Nanotechnology JT - Nanotechnology JID - 101241272 EDAT- 2011/05/06 06:00 MHDA- 2011/05/06 06:01 CRDT- 2011/05/06 06:00 PHST- 2011/05/06 06:00 [entrez] PHST- 2011/05/06 06:00 [pubmed] PHST- 2011/05/06 06:01 [medline] AID - S0957-4484(11)83427-6 [pii] AID - 10.1088/0957-4484/22/24/245306 [doi] PST - ppublish SO - Nanotechnology. 2011 Jun 17;22(24):245306. doi: 10.1088/0957-4484/22/24/245306. Epub 2011 May 4.