PMID- 21574632
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20110929
LR  - 20110615
IS  - 1520-5126 (Electronic)
IS  - 0002-7863 (Linking)
VI  - 133
IP  - 24
DP  - 2011 Jun 22
TI  - Layer-by-layer assembly and UV photoreduction of graphene-polyoxometalate 
      composite films for electronics.
PG  - 9423-9
LID - 10.1021/ja201594k [doi]
AB  - Graphene oxide (GO) nanosheets and polyoxometalate clusters, H(3)PW(12)O(40) 
      (PW), were co-assembled into multilayer films via electrostatic layer-by-layer 
      assembly. Under UV irradiation, a photoreduction reaction took place in the films 
      which converted GO to reduced GO (rGO) due to the photocatalytic activity of PW 
      clusters. By this means, uniform and large-area composite films based on rGO were 
      fabricated with precisely controlled thickness on various substrates such as 
      quartz, silicon, and plastic supports. We further fabricated field effect 
      transistors based on the composite films, which exhibited typical ambipolar 
      features and good transport properties for both holes and electrons. The on/off 
      ratios and the charge carrier mobilities of the transistors depend on the number 
      of deposited layers and can be controlled easily. Furthermore, we used photomasks 
      to produce conductive patterns of rGO domains on the films, which served as 
      efficient microelectrodes for photodetector devices.
FAU - Li, Haolong
AU  - Li H
AD  - Max Planck Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz, 
      Germany.
FAU - Pang, Shuping
AU  - Pang S
FAU - Wu, Si
AU  - Wu S
FAU - Feng, Xinliang
AU  - Feng X
FAU - Mullen, Klaus
AU  - Mullen K
FAU - Bubeck, Christoph
AU  - Bubeck C
LA  - eng
PT  - Journal Article
DEP - 20110525
PL  - United States
TA  - J Am Chem Soc
JT  - Journal of the American Chemical Society
JID - 7503056
EDAT- 2011/05/18 06:00
MHDA- 2011/05/18 06:01
CRDT- 2011/05/18 06:00
PHST- 2011/05/18 06:00 [entrez]
PHST- 2011/05/18 06:00 [pubmed]
PHST- 2011/05/18 06:01 [medline]
AID - 10.1021/ja201594k [doi]
PST - ppublish
SO  - J Am Chem Soc. 2011 Jun 22;133(24):9423-9. doi: 10.1021/ja201594k. Epub 2011 May 
      25.