PMID- 21588485
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20110714
LR  - 20211020
IS  - 1600-5368 (Electronic)
IS  - 1600-5368 (Linking)
VI  - 66
IP  - Pt 9
DP  - 2010 Aug 4
TI  - Dicyanidobis(N,N'-dimethythio-urea-kappaS)mercury(II).
PG  - m1060-1
LID - 10.1107/S1600536810030424 [doi]
AB  - In the title complex, [Hg(CN)(2)(C(3)H(8)N(2)S)(2)], the Hg(II) atom is located 
      on a twofold rotation axis. It is four-coordinate having an irregular 
      tetra-hedral geometry composed of two cyanide C atoms [Hg-C = 2.090 (6) A] and 
      two thione S atoms of N,N'-dimethyl-thio-urea (dmtu) [Hg-S = 2.7114 (9) A]. The 
      NC-Hg-CN bond angle of 148.83 (13) degrees  has the greatest deviation from the ideal 
      tetra-hedral geometry. The mol-ecular structure is stabilized by intra-molecular 
      N-Hcdots, three dots, centeredS inter-actions involving dmtu units related by the twofold symmetry. In the 
      crystal, inter-molecular N-Hcdots, three dots, centeredN(CN) hydrogen-bonding inter-actions link 
      symmetry-related mol-ecules into a two-dimensional network in (110).
FAU - Riaz Malik, Muhammad
AU  - Riaz Malik M
FAU - Ali, Saqib
AU  - Ali S
FAU - Ahmad, Saeed
AU  - Ahmad S
FAU - Altaf, Muhammad
AU  - Altaf M
FAU - Stoeckli-Evans, Helen
AU  - Stoeckli-Evans H
LA  - eng
PT  - Journal Article
DEP - 20100804
PL  - United States
TA  - Acta Crystallogr Sect E Struct Rep Online
JT  - Acta crystallographica. Section E, Structure reports online
JID - 101089178
PMC - PMC3008114
EDAT- 2010/01/01 00:00
MHDA- 2010/01/01 00:01
PMCR- 2010/08/04
CRDT- 2011/05/19 06:00
PHST- 2010/07/29 00:00 [received]
PHST- 2010/07/30 00:00 [accepted]
PHST- 2011/05/19 06:00 [entrez]
PHST- 2010/01/01 00:00 [pubmed]
PHST- 2010/01/01 00:01 [medline]
PHST- 2010/08/04 00:00 [pmc-release]
AID - wm2389 [pii]
AID - 10.1107/S1600536810030424 [doi]
PST - epublish
SO  - Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 4;66(Pt 9):m1060-1. doi: 
      10.1107/S1600536810030424.