PMID- 21688391
OWN - NLM
STAT- MEDLINE
DCOM- 20151005
LR  - 20191210
IS  - 1615-9314 (Electronic)
IS  - 1615-9306 (Linking)
VI  - 34
IP  - 16-17
DP  - 2011 Aug
TI  - Aminopropyltriethoxysilane-silica hybrid monolithic capillary microextraction 
      combined with inductively coupled plasma mass spectrometry for the determination 
      of trace elements in biological samples.
PG  - 2247-54
LID - 10.1002/jssc.201100173 [doi]
AB  - A simple and sensitive method based on aminopropyltriethoxysilane (APTES)-silica 
      hybrid monolithic capillary microextraction (CME) combined with inductively 
      coupled plasma mass spectrometry (ICP-MS) was developed for the determination of 
      trace elements in biological samples. Under the optimized conditions, the 
      adsorption capacities of APTES-silica hybrid monolithic capillary were 42.5, 55, 
      57.5, 82.5, 52.5, and 40 mug/m for Mn(II), Co(II), Ni(II), Cu(II), Cd(II), and 
      Pb(II), respectively. The LODs were in the range of 1.2 (Cd)-14 (Pb) ng/L with 
      the relative standard deviations (RSDs) of <5.1% (c=1 mug/L, n=7). The 
      reproducibility of APTES-silica hybrid monolithic preparation ranged from 1.6 to 
      5.6% in one batch, and from 2.3 to 6.2% in batch-to-batch, respectively. To 
      validate the developed method, two certified reference materials of NIES No. 10-b 
      rice flour and GBW 07601 (GSH-1) human hair were analyzed and the determined 
      values were in good agreement with the certified values. The proposed method has 
      also been applied for the analysis of human hair and urine samples with the 
      recoveries for the spiked samples in the range of 89-106%.
CI  - Copyright (c) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Zhang, Lin
AU  - Zhang L
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of 
      Education), Department of Chemistry, Wuhan University, Wuhan, P. R. China.
FAU - Chen, Beibei
AU  - Chen B
FAU - Peng, Hanyong
AU  - Peng H
FAU - He, Man
AU  - He M
FAU - Hu, Bin
AU  - Hu B
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20110620
PL  - Germany
TA  - J Sep Sci
JT  - Journal of separation science
JID - 101088554
RN  - 0 (Propylamines)
RN  - 0 (Silanes)
RN  - 0 (Trace Elements)
RN  - 7631-86-9 (Silicon Dioxide)
RN  - L8S6UBW552 (amino-propyl-triethoxysilane)
SB  - IM
MH  - Hair/*chemistry
MH  - Humans
MH  - Limit of Detection
MH  - Mass Spectrometry/*methods
MH  - Propylamines
MH  - Silanes/chemistry
MH  - Silicon Dioxide/chemistry
MH  - Solid Phase Microextraction/instrumentation/*methods
MH  - Trace Elements/*analysis/*isolation & purification
MH  - Urine/*chemistry
OTO - NOTNLM
OT  - APTES-silica monolithic capillary
OT  - Biological samples
OT  - Capillary microextraction
OT  - Inductively coupled plasma mass spectrometry
EDAT- 2011/06/21 06:00
MHDA- 2015/10/06 06:00
CRDT- 2011/06/21 06:00
PHST- 2011/03/02 00:00 [received]
PHST- 2011/05/01 00:00 [revised]
PHST- 2011/05/02 00:00 [accepted]
PHST- 2011/06/21 06:00 [entrez]
PHST- 2011/06/21 06:00 [pubmed]
PHST- 2015/10/06 06:00 [medline]
AID - 10.1002/jssc.201100173 [doi]
PST - ppublish
SO  - J Sep Sci. 2011 Aug;34(16-17):2247-54. doi: 10.1002/jssc.201100173. Epub 2011 Jun 
      20.