PMID- 21727490 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20121002 LR - 20110705 IS - 0957-4484 (Print) IS - 0957-4484 (Linking) VI - 17 IP - 10 DP - 2006 May 28 TI - Synthesis and characterization of water-soluble multiwalled carbon nanotubes grafted by a thermoresponsive polymer. PG - 2458-65 LID - 10.1088/0957-4484/17/10/005 [doi] AB - Water-soluble multiwalled carbon nanotubes (MWNTs) with temperature-responsive shells were successfully prepared by grafting poly (N-isopropylacrylamide) (PNIPAM) from the sidewalls of MWNTs, via surface reversible addition-fragmentation chain transfer (RAFT) polymerization using RAFT agent functionalized MWNTs as the chain transfer agent. Thermogravimetric analysis (TGA) measurements showed that the weight composition of the as-grown PNIPAM polymers on the MWNTs can be well controlled by the feed ratio (in weight) of NIPAM to RAFT agent functionalized MWNTs (MWNT-SC(S)Ph). The MWNT-g-PNIPAM has good solubility in water, chloroform, and tetrahydrofuran (THF). Transmission electron microscope (TEM) and scanning electron microscope (SEM) images also showed that the MWNT-g-PNIPAM was dispersed individually and eventually bonded with the polymer layer by surface RAFT polymerization. The PNIPAM shell is very sensitive to a change of temperature. This method could find potential applications by grafting other functional polymer chains onto MWNTs. FAU - Xu, Guoyong AU - Xu G AD - Hefei National Laboratory for Physical Sciences at the Microscale, Structure Research Laboratory, University of Science and Technology of China, Chinese Academy of Sciences, Hefei 230026, People's Republic of China. FAU - Wu, Wei-Tai AU - Wu WT FAU - Wang, Yusong AU - Wang Y FAU - Pang, Wenmin AU - Pang W FAU - Wang, Pinghua AU - Wang P FAU - Zhu, Qingren AU - Zhu Q FAU - Lu, Fei AU - Lu F LA - eng PT - Journal Article DEP - 20060424 PL - England TA - Nanotechnology JT - Nanotechnology JID - 101241272 EDAT- 2006/05/28 00:00 MHDA- 2006/05/28 00:01 CRDT- 2011/07/06 06:00 PHST- 2011/07/06 06:00 [entrez] PHST- 2006/05/28 00:00 [pubmed] PHST- 2006/05/28 00:01 [medline] AID - S0957-4484(06)15732-3 [pii] AID - 10.1088/0957-4484/17/10/005 [doi] PST - ppublish SO - Nanotechnology. 2006 May 28;17(10):2458-65. doi: 10.1088/0957-4484/17/10/005. Epub 2006 Apr 24.