PMID- 21770247
OWN - NLM
STAT- MEDLINE
DCOM- 20120816
LR  - 20190923
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 29
IP  - 4
DP  - 2011 Apr
TI  - [Determination of organotin compounds in textile auxiliaries by gas 
      chromatography-mass spectrometry].
PG  - 353-7
AB  - A gas chromatography-mass spectrometry (GC-MS) method has been developed for the 
      determination of dibutyltin (DBT), tributyltin (TBT) and triphenyltin (TPhT) in 
      textile auxiliaries. The sample was first extracted with n-hexane in acetate 
      buffer solution (pH 4.0) under ultrasonication (for hydrophobic sample) or 
      oscillation extraction (for hydrophilic sample) and then derivatized with sodium 
      tetraethylborate in tetrahydrofuran. The derivative was determined by GC-MS in 
      selected ion monitoring (SIM) mode. The separation and quantification were 
      achieved using a Rxi-5 ms silica capillary column (30 m x 0.25 mm x 0.25 microm). 
      The linear ranges were 0.1-8.0 mg/L for both DBT and TBT, and 0.1-4.0 mg/L for 
      TPhT. There were good linear relationships between the peak area and 
      concentration in the linear ranges and the correlation coefficients (r2) were 
      0.9994-0.9998. The detection limits (LOD) were from 0.003 mg/L to 0.005 mg/L. The 
      average recoveries of these organotin compounds at the three spiked levels of 
      4.0, 10.0 and 40.0 mg/kg were 92.6%-108.0% with the relative standard deviations 
      (RSDs) of 2.5%-10.2%. The method is simple and accurate for simultaneous analysis 
      of the DBT, TBT and TPhT in textile auxiliaries.
FAU - Li, Yanming
AU  - Li Y
AD  - Dymatic Chemicals, Inc., Shunde 528305, China.
FAU - Hu, Yongjie
AU  - Hu Y
FAU - Liu, Jinhua
AU  - Liu J
FAU - Guo, Yuliang
AU  - Guo Y
FAU - Wang, Guiqin
AU  - Wang G
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Organotin Compounds)
RN  - 0 (Trialkyltin Compounds)
RN  - 1002-53-5 (di-n-butyltin)
RN  - 4XDX163P3D (tributyltin)
RN  - 95T92AGN0V (triphenyltin)
SB  - IM
MH  - Gas Chromatography-Mass Spectrometry/*methods
MH  - Organotin Compounds/*analysis
MH  - *Textile Industry
MH  - Trialkyltin Compounds/*analysis
EDAT- 2011/07/21 06:00
MHDA- 2012/08/17 06:00
CRDT- 2011/07/21 06:00
PHST- 2011/07/21 06:00 [entrez]
PHST- 2011/07/21 06:00 [pubmed]
PHST- 2012/08/17 06:00 [medline]
AID - 10.3724/sp.j.1123.2011.00353 [doi]
PST - ppublish
SO  - Se Pu. 2011 Apr;29(4):353-7. doi: 10.3724/sp.j.1123.2011.00353.