PMID- 21780700
OWN - NLM
STAT- MEDLINE
DCOM- 20110823
LR  - 20141120
IS  - 0959-3330 (Print)
IS  - 0959-3330 (Linking)
VI  - 32
IP  - 3-4
DP  - 2011 Feb-Mar
TI  - Effective separation and sensitive determination of cyanuric acid, melamine and 
      cyromazine in environmental water by reversed phase high-performance liquid 
      chromatography.
PG  - 317-23
AB  - A new method for the simultaneous determination of cyanuric acid (CA), melamine 
      (MM) and cyromazine (CM) in different water samples was developed by using 
      reversed phase high-performance liquid chromatography diode-array detection 
      (RP-HPLC-DAD). The conditions of HPLC were investigated and optimized. A KROMASIL 
      C18 column (250 x 4.6 mm ID, 5 microm) was used for the RP-HPLC using gradient 
      elution with a mobile phase composed of 0.1 mM KH2PO4-K2HPO4 buffer solution (pH 
      = 7.3) and methanol (75:25, v/v). The conditions for HPLC were investigated and 
      optimized. Under optimal conditions, the linearity was satisfactory in the range 
      of 0.04-10.00 microg/mL with a correlation coefficient of 0.999, and the method 
      limits of detection (LODs) of the proposed method were 0.02 microg/mL for CA and 
      CM, and 0.01 microg/mL for MM. The recoveries were: 96.0-116.0% with relative 
      standard deviations (RSDs) of 0.9-5.7% for CA, 94.3-115.0% with RSDs of 1.5-5.3% 
      for MM, and 91.0-112.0% with RSDs (n = 6) of 1.0-4.9% for CM. The proposed method 
      can permit the detection of CA and CM at levels as low as 0.07 microg/mL and MM 
      at levels as low as 0.03 microg/mL in environmental water samples.
FAU - Sun, Hanwen
AU  - Sun H
AD  - College of Chemistry and Environmental Science, Hebei University, Key Laboratory 
      of Analytical Science and Technology of Hebei Province, Baoding 071002, China. 
      hanwen@hbu.edu.cn
FAU - Qin, Xiaolan
AU  - Qin X
FAU - Ge, Xusheng
AU  - Ge X
FAU - Wang, Lixin
AU  - Wang L
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - England
TA  - Environ Technol
JT  - Environmental technology
JID - 9884939
RN  - 0 (Insecticides)
RN  - 0 (Triazines)
RN  - 0 (Water Pollutants, Chemical)
RN  - CA49Y29RA9 (cyromazine)
RN  - H497R4QKTZ (cyanuric acid)
RN  - N3GP2YSD88 (melamine)
SB  - IM
MH  - Chromatography, High Pressure Liquid/*methods
MH  - Insecticides/analysis/isolation & purification
MH  - Limit of Detection
MH  - Triazines/analysis/*isolation & purification
MH  - Water Pollutants, Chemical/analysis/*isolation & purification
EDAT- 2011/07/26 06:00
MHDA- 2011/08/24 06:00
CRDT- 2011/07/26 06:00
PHST- 2011/07/26 06:00 [entrez]
PHST- 2011/07/26 06:00 [pubmed]
PHST- 2011/08/24 06:00 [medline]
AID - 10.1080/09593330.2010.499543 [doi]
PST - ppublish
SO  - Environ Technol. 2011 Feb-Mar;32(3-4):317-23. doi: 10.1080/09593330.2010.499543.