PMID- 21848321 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20120113 LR - 20110913 IS - 1520-5827 (Electronic) IS - 0743-7463 (Linking) VI - 27 IP - 18 DP - 2011 Sep 20 TI - Shear adhesion strength of thermoplastic gecko-inspired synthetic adhesive exceeds material limits. PG - 11278-81 LID - 10.1021/la202085j [doi] AB - Natural gecko array wearless dynamic friction has recently been reported for 30,000 cycles on a smooth substrate. Following these findings, stiff polymer gecko-inspired synthetic adhesives have been proposed for high-cycle applications such as robot feet. Here we examine the behavior of high-density polyethylene (HDPE) and polypropylene (PP) microfiber arrays during repeated cycles of engagement on a glass surface, with a normal preload of less than 40 kPa. We find that fiber arrays maintained 54% of the original shear stress of 300 kPa after 10,000 cycles, despite showing a marked plastic deformation of fiber tips. This deformation could be due to shear-induced plastic creep of the fiber tips from high adhesion forces, adhesive wear, or thermal effects. We hypothesize that a fundamental material limit has been reached for these fiber arrays and that future gecko synthetic adhesive designs must take into account the high adhesive forces generated to avoid damage. Although the synthetic material and natural gecko arrays have a similar elastic modulus, the synthetic material does not show the same wear-free dynamic friction as the gecko. CI - (c) 2011 American Chemical Society FAU - Gillies, Andrew G AU - Gillies AG AD - Department of Mechanical Engineering, University of California, Berkeley, California 94720, USA. andrew.gillies@berkeley.edu FAU - Fearing, Ronald S AU - Fearing RS LA - eng PT - Journal Article DEP - 20110823 PL - United States TA - Langmuir JT - Langmuir : the ACS journal of surfaces and colloids JID - 9882736 EDAT- 2011/08/19 06:00 MHDA- 2011/08/19 06:01 CRDT- 2011/08/19 06:00 PHST- 2011/08/19 06:00 [entrez] PHST- 2011/08/19 06:00 [pubmed] PHST- 2011/08/19 06:01 [medline] AID - 10.1021/la202085j [doi] PST - ppublish SO - Langmuir. 2011 Sep 20;27(18):11278-81. doi: 10.1021/la202085j. Epub 2011 Aug 23.