PMID- 21967829 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20120123 LR - 20111005 IS - 1361-6528 (Electronic) IS - 0957-4484 (Linking) VI - 22 IP - 43 DP - 2011 Oct 28 TI - Bandgap engineering of zigzag graphene nanoribbons by manipulating edge states via defective boundaries. PG - 435702 LID - 10.1088/0957-4484/22/43/435702 [doi] AB - One of the most severe limits of graphene nanoribbons (GNRs) in future applications is that zigzag GNRs (ZGNRs) are gapless, so cannot be used in field effect transistors (FETs), and armchair GNR (AGNR) based FETs require atomically precise control of edges and width. Using the tight-binding approach and first principles method, we derived and proved a general boundary condition for the opening of a significant bandgap in ZGNRs with defective edge structures. The proposed semiconducting ZGNRs have some interesting properties one of which is that they can be embedded and integrated in a large piece of graphene without the need to completely cut them out. We also demonstrated a new type of high-performance all-ZGNR FET. Previous proposals of graphene FETs are all based on AGNRs. FAU - Zhang, Aihua AU - Zhang A AD - Department of Physics, National University of Singapore, 117542, Singapore. FAU - Wu, Yihong AU - Wu Y FAU - Ke, San-Huang AU - Ke SH FAU - Feng, Yuan Ping AU - Feng YP FAU - Zhang, Chun AU - Zhang C LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20111003 PL - England TA - Nanotechnology JT - Nanotechnology JID - 101241272 EDAT- 2011/10/05 06:00 MHDA- 2011/10/05 06:01 CRDT- 2011/10/05 06:00 PHST- 2011/10/05 06:00 [entrez] PHST- 2011/10/05 06:00 [pubmed] PHST- 2011/10/05 06:01 [medline] AID - S0957-4484(11)96080-2 [pii] AID - 10.1088/0957-4484/22/43/435702 [doi] PST - ppublish SO - Nanotechnology. 2011 Oct 28;22(43):435702. doi: 10.1088/0957-4484/22/43/435702. Epub 2011 Oct 3.