PMID- 22029282
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20120315
LR  - 20111124
IS  - 1520-5207 (Electronic)
IS  - 1520-5207 (Linking)
VI  - 115
IP  - 47
DP  - 2011 Dec 1
TI  - Analysis of the lamellar structure of semicrystalline polymers by direct model 
      fitting of SAXS patterns.
PG  - 13803-8
LID - 10.1021/jp204998p [doi]
AB  - Small-angle X-ray scattering data of melt-drawn high-density polyethylene (HDPE) 
      have been analyzed by direct model fitting to projections on the drawing 
      direction. On the basis of the assumption of an infinite paracrystalline lattice 
      as proposed by Hosemann and a rectangular density profile, several additional 
      assumptions have been tested. It turned out that to achieve good fits we have to 
      introduce a finiteness of the lattice for the used samples. Transition zones 
      between crystalline and amorphous regions also improve the model but are of less 
      importance. The most suitable model has been tested on data from an annealing and 
      subsequent cooling process. We show that the additional parameters gained in the 
      modeling approach compared to peak analysis or correlation function analysis lead 
      to a better understanding of the structures and processes in the samples.
CI  - (c) 2011 American Chemical Society
FAU - Fischer, Stefan
AU  - Fischer S
AD  - State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of 
      Applied Chemistry, Renmin Street 5625, Changchun, PR China, 130022, People's 
      Republic of China.
FAU - Jiang, Zhiyong
AU  - Jiang Z
FAU - Men, Yongfeng
AU  - Men Y
LA  - eng
PT  - Journal Article
DEP - 20111107
PL  - United States
TA  - J Phys Chem B
JT  - The journal of physical chemistry. B
JID - 101157530
EDAT- 2011/10/28 06:00
MHDA- 2011/10/28 06:01
CRDT- 2011/10/28 06:00
PHST- 2011/10/28 06:00 [entrez]
PHST- 2011/10/28 06:00 [pubmed]
PHST- 2011/10/28 06:01 [medline]
AID - 10.1021/jp204998p [doi]
PST - ppublish
SO  - J Phys Chem B. 2011 Dec 1;115(47):13803-8. doi: 10.1021/jp204998p. Epub 2011 Nov 
      7.